Conversion of biomass-derived carbohydrates into 5-hydroxymethylfurfural catalyzed by sulfonic acid-functionalized carbon material with high strong-acid density in gamma-valerolactone

doi:10.1007/s11164-018-3432-y

GIEC OpenIR

	Conversion of biomass-derived carbohydrates into 5-hydroxymethylfurfural catalyzed by sulfonic acid-functionalized carbon material with high strong-acid density in gamma-valerolactone
	Huang, Feng 1; Li, Wenzhi 1; Zhang, Tingwei 1; Li, Dawei 2; Liu, Qiyu 1; Zhu, Xifeng 1; Ma, Longlong3
	2018-09-01
发表期刊	RESEARCH ON CHEMICAL INTERMEDIATES
ISSN	0922-6168
卷号	44 期号:9 页码:5439-5453
通讯作者	Li, Wenzhi(liwenzhi@ustc.edu.cn)
摘要	A carbonaceous solid acid catalyst with high strong-acid density was synthesized by facile functionalization of a biomass-derived mesoporous carbon with benzenesulfonic acid. The catalyst was characterized by using Fourier transform infrared spectroscopy, elemental analysis, X-ray photoelectron spectroscopy, transmission electron microscopy, and N-2 adsorption-desorption. The carbonaceous solid catalyst containing Bronsted acid sites was used for the production of 5-hydroxymethylfurfural (HMF) from hexoses such as fructose, glucose, and cellulose in gamma-valerolactone (GVL)-H2O mixture. By reaction at 130 degrees C for 20 min using fructose as a feedstock, an HMF yield 78.1% was achieved. The catalytic performance of the catalyst in conversion of fructose into HMF hardly changed over seven cycles, demonstrating that the catalyst had excellent recyclability. The yields of HMF derived from glucose and cellulose reached 33.2 and 22.5%, respectively, whereas those of total furans were 42.1 and 33.7%, respectively. The proposed reaction system was promising in transforming biomass-based carbohydrates into fine chemicals, given the use of green functionalization methods, the utilization of sustainable biomass-derived carbon precursor and solvents, catalyst with high acid density, and the availability of high HMF yield.
关键词	Carbohydrate Fructose Glucose 5-Hydroxymethylfurfural gamma-Valerolactone Carbon solid acid
DOI	10.1007/s11164-018-3432-y
关键词[WOS]	IONIC LIQUID ; SELECTIVE CONVERSION ; AQUEOUS-MEDIA ; CORN STALK ; FRUCTOSE ; GLUCOSE ; DEHYDRATION ; HMF ; 5-HMF ; CELLULOSE
收录类别	SCI
语种	英语
资助项目	State Key Program of National Natural Science Foundation of China[51536009] ; Science and Technological Fund of Anhui Province for Outstanding Youth[1508085J01] ; National Key Technology R&D Program of China[2015BAD15B06]
WOS研究方向	Chemistry
项目资助者	State Key Program of National Natural Science Foundation of China ; Science and Technological Fund of Anhui Province for Outstanding Youth ; National Key Technology R&D Program of China
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000441789200029
出版者	SPRINGER
引用统计	被引频次：15[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/23770
专题	中国科学院广州能源研究所
通讯作者	Li, Wenzhi
作者单位	1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Anhui, Peoples R China 2.China Univ Petr East China, State Key Lab Heavy Oil Proc, Qingdao 266580, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Huang, Feng,Li, Wenzhi,Zhang, Tingwei,et al. Conversion of biomass-derived carbohydrates into 5-hydroxymethylfurfural catalyzed by sulfonic acid-functionalized carbon material with high strong-acid density in gamma-valerolactone[J]. RESEARCH ON CHEMICAL INTERMEDIATES,2018,44(9):5439-5453.
APA	Huang, Feng.,Li, Wenzhi.,Zhang, Tingwei.,Li, Dawei.,Liu, Qiyu.,...&Ma, Longlong.(2018).Conversion of biomass-derived carbohydrates into 5-hydroxymethylfurfural catalyzed by sulfonic acid-functionalized carbon material with high strong-acid density in gamma-valerolactone.RESEARCH ON CHEMICAL INTERMEDIATES,44(9),5439-5453.
MLA	Huang, Feng,et al."Conversion of biomass-derived carbohydrates into 5-hydroxymethylfurfural catalyzed by sulfonic acid-functionalized carbon material with high strong-acid density in gamma-valerolactone".RESEARCH ON CHEMICAL INTERMEDIATES 44.9(2018):5439-5453.