Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Selective yields of furfural and hydroxymethylfurfural from glucose in tetrahydrofuran over H beta zeolite | |
Tan, Jin1,2,3; Wang, Haiyong1,2,3; Ma, Longlong1,2,3 ; Wang, Chenguang1,2,3; Liu, Qiying1,2,3; Zhang, Qi1,2,3; He, Minghong1,2,3
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| 2018 | |
| Source Publication | RSC ADVANCES
 |
| ISSN | 2046-2069 |
| Volume | 8Issue:43Pages:24534-24540 |
| Corresponding Author | Ma, Longlong(mall@ms.giec.ac.cn) |
| Abstract | Several simple and effective solvents combined with H beta zeolite were tested to selectively convert glucose into furfural and hydroxymethylfurfural in this work. The physicochemical properties of typically different polar aprotic solvents were compared. Tetrahydrofuran was found to be a suitable solvent in the selective conversion of glucose. The effect of reaction parameters, such as temperature, reaction time, water content, glucose dosage and protonic acid addition, on the product distribution were investigated in detail. Furfural and hydroxymethylfurfural could be selectively produced in this system, and the highest yields of furfural and hydroxymethylfurfural were up to 35.2% and 49.7% respectively. Furfural could be stable in a tetrahydrofuran medium when adding 5 wt% water in the absence of extra protonic acid. However, furfural production was extremely suppressed after addition of an acidic inorganic salt, which increased the yield of hydroxymethylfurfural. This investigation indicates a simple and feasible method to selectively produce furfural and hydroxymethylfurfural from renewable cellulosic carbohydrates. |
| DOI | 10.1039/c8ra04060e |
| WOS Keyword | BIOMASS CONVERSION REACTIONS ; ACID-CATALYZED CONVERSION ; GAMMA-VALEROLACTONE ; LEVULINIC ACID ; SUPERCRITICAL WATER ; ETHYL LEVULINATE ; BIPHASIC SYSTEM ; SOLVENT ; FRUCTOSE ; DEHYDRATION |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[51536009] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092] ; Natural Science Foundation of Guangdong Province[2017A030308010] |
| WOS Research Area | Chemistry |
| Funding Organization | National Natural Science Foundation of China ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program ; Natural Science Foundation of Guangdong Province |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000440243600051 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/23677 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Ma, Longlong |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Tan, Jin,Wang, Haiyong,Ma, Longlong,et al. Selective yields of furfural and hydroxymethylfurfural from glucose in tetrahydrofuran over H beta zeolite[J]. RSC ADVANCES,2018,8(43):24534-24540. |
| APA | Tan, Jin.,Wang, Haiyong.,Ma, Longlong.,Wang, Chenguang.,Liu, Qiying.,...&He, Minghong.(2018).Selective yields of furfural and hydroxymethylfurfural from glucose in tetrahydrofuran over H beta zeolite.RSC ADVANCES,8(43),24534-24540. |
| MLA | Tan, Jin,et al."Selective yields of furfural and hydroxymethylfurfural from glucose in tetrahydrofuran over H beta zeolite".RSC ADVANCES 8.43(2018):24534-24540. |
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