Selective yields of furfural and hydroxymethylfurfural from glucose in tetrahydrofuran over H beta zeolite

doi:10.1039/c8ra04060e

GIEC OpenIR

	Selective yields of furfural and hydroxymethylfurfural from glucose in tetrahydrofuran over H beta zeolite
	Tan, Jin 1,2,3; Wang, Haiyong 1,2,3; Ma, Longlong1,2,3 ; Wang, Chenguang 1,2,3; Liu, Qiying1,2,3 ; Zhang, Qi1,2,3 ; He, Minghong1,2,3
	2018
发表期刊	RSC ADVANCES
ISSN	2046-2069
卷号	8 期号:43 页码:24534-24540
通讯作者	Ma, Longlong(mall@ms.giec.ac.cn)
摘要	Several simple and effective solvents combined with H beta zeolite were tested to selectively convert glucose into furfural and hydroxymethylfurfural in this work. The physicochemical properties of typically different polar aprotic solvents were compared. Tetrahydrofuran was found to be a suitable solvent in the selective conversion of glucose. The effect of reaction parameters, such as temperature, reaction time, water content, glucose dosage and protonic acid addition, on the product distribution were investigated in detail. Furfural and hydroxymethylfurfural could be selectively produced in this system, and the highest yields of furfural and hydroxymethylfurfural were up to 35.2% and 49.7% respectively. Furfural could be stable in a tetrahydrofuran medium when adding 5 wt% water in the absence of extra protonic acid. However, furfural production was extremely suppressed after addition of an acidic inorganic salt, which increased the yield of hydroxymethylfurfural. This investigation indicates a simple and feasible method to selectively produce furfural and hydroxymethylfurfural from renewable cellulosic carbohydrates.
DOI	10.1039/c8ra04060e
关键词[WOS]	BIOMASS CONVERSION REACTIONS ; ACID-CATALYZED CONVERSION ; GAMMA-VALEROLACTONE ; LEVULINIC ACID ; SUPERCRITICAL WATER ; ETHYL LEVULINATE ; BIPHASIC SYSTEM ; SOLVENT ; FRUCTOSE ; DEHYDRATION
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51536009] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092] ; Natural Science Foundation of Guangdong Province[2017A030308010]
WOS研究方向	Chemistry
项目资助者	National Natural Science Foundation of China ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program ; Natural Science Foundation of Guangdong Province
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000440243600051
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：11[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/23677
专题	中国科学院广州能源研究所
通讯作者	Ma, Longlong
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Tan, Jin,Wang, Haiyong,Ma, Longlong,et al. Selective yields of furfural and hydroxymethylfurfural from glucose in tetrahydrofuran over H beta zeolite[J]. RSC ADVANCES,2018,8(43):24534-24540.
APA	Tan, Jin.,Wang, Haiyong.,Ma, Longlong.,Wang, Chenguang.,Liu, Qiying.,...&He, Minghong.(2018).Selective yields of furfural and hydroxymethylfurfural from glucose in tetrahydrofuran over H beta zeolite.RSC ADVANCES,8(43),24534-24540.
MLA	Tan, Jin,et al."Selective yields of furfural and hydroxymethylfurfural from glucose in tetrahydrofuran over H beta zeolite".RSC ADVANCES 8.43(2018):24534-24540.