Production of renewable long-chained cycloalkanes from biomass-derived furfurals and cyclic ketones

doi:10.1039/c8ra01723a

GIEC OpenIR

	Production of renewable long-chained cycloalkanes from biomass-derived furfurals and cyclic ketones
	Liu, Qiying1 ; Zhang, Caihong 1,2; Shi, Ning 1,2; Zhang, Xinghua1 ; Wang, Chenguang 1; Ma, Longlong1
	2018
发表期刊	RSC ADVANCES
ISSN	2046-2069
卷号	8 期号:25 页码:13686-13696
通讯作者	Liu, Qiying(liuqy@ms.giec.ac.cn) ; Zhang, Xinghua(zhangxh@ms.giec.ac.cn)
摘要	Developing renewable long-chain cycloalkanes from lignocellulosic biomass is of significance because it offers huge resource storage, wide applications in aviation/diesel fuels and mitigation of CO2 emissions. In this paper, cycloalkanes with carbon chain lengths of 13-18 were produced from biomass-derived furfural species (furfural and 5-hydroxymethylfurfural) and cyclic ketones (cyclopentanone and cyclohexanone) via aldol condensation, followed by hydrogenation to saturate the C?C and C?O bonds, and hydrodeoxygenation to remove oxygen atoms. The aldol condensation of the furfural species with cyclic ketones was catalyzed by NaOH and the target condensation intermediates were obtained in yields of more than 90% at room temperature (30 degrees C) with a short reaction time (40 min). By using amorphous zirconium phosphate combined with Pd/C as the catalyst, liquid cycloalkanes were produced at the optimal conditions with a yield of 76%. When the combined solid catalyst was reused, the target products reduced after the second run but the initial yield could be largely recovered by recalcination of the spent zirconium phosphate. Considering that cyclopentanone and cyclohexanone can be easily produced from furfural (originating from hemicellulose) and phenol (originating from lignin), respectively, this condensation has the potential to achieve the integrated conversion of biomass-derived cellulose, hemicellulose and lignin to jet fuel and/or diesel additives.
DOI	10.1039/c8ra01723a
关键词[WOS]	HIGH-QUALITY DIESEL ; RAW LIGNOCELLULOSIC BIOMASS ; FUEL RANGE ALKANES ; DROP-IN BIOFUELS ; ZIRCONIUM-PHOSPHATE ; JET FUEL ; PLATFORM MOLECULES ; ALDOL CONDENSATION ; ANGELICA LACTONE ; LIQUID ALKANES
收录类别	SCI
语种	英语
资助项目	Natural Science Foundation of China[51536009] ; Natural Science Foundation of China[51576199] ; Natural Science Foundation of China[51376185] ; Natural Science Foundation of Guangdong Province[2017A030308010]
WOS研究方向	Chemistry
项目资助者	Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000430538300009
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：27[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/23260
专题	中国科学院广州能源研究所
通讯作者	Liu, Qiying; Zhang, Xinghua
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510650, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Liu, Qiying,Zhang, Caihong,Shi, Ning,et al. Production of renewable long-chained cycloalkanes from biomass-derived furfurals and cyclic ketones[J]. RSC ADVANCES,2018,8(25):13686-13696.
APA	Liu, Qiying,Zhang, Caihong,Shi, Ning,Zhang, Xinghua,Wang, Chenguang,&Ma, Longlong.(2018).Production of renewable long-chained cycloalkanes from biomass-derived furfurals and cyclic ketones.RSC ADVANCES,8(25),13686-13696.
MLA	Liu, Qiying,et al."Production of renewable long-chained cycloalkanes from biomass-derived furfurals and cyclic ketones".RSC ADVANCES 8.25(2018):13686-13696.