Catalytic Transfer Hydrogenation of Ethyl Levulinate into gamma-Valerolactone Over Zirconium Oxide Derived from Zirconyl Nitrate

doi:10.1166/jbmb.2017.1717

GIEC OpenIR

	Catalytic Transfer Hydrogenation of Ethyl Levulinate into gamma-Valerolactone Over Zirconium Oxide Derived from Zirconyl Nitrate
	Dong, Kaijun1,2,3 ; Zhang, Jun 1,2,3; Luo, Weimin1,2,3 ; Su, Lin 1,2,3; Huang, Zhilin 1,2,3,4
	2017-12-01
发表期刊	JOURNAL OF BIOBASED MATERIALS AND BIOENERGY
ISSN	1556-6560
卷号	11 期号:6 页码:543-552
通讯作者	Zhang, Jun(zhangjun@ms.giec.ac.cn)
摘要	A series of zirconium based catalysts were synthesized to study the transfer hydrogenation of biomass derived ethyl levulinate into gamma-valerolactone (GVL) using lower alcohols as hydrogen donors. The essential textural and chemical characteristics of prepared samples were identified by various techniques including SEM, XRD, NH3-TPD, TGA, CO2-TPD and nitrogen physisorption. Parameters such as hydrogen donor, catalyst type, temperature, stirring rate, and catalyst dosage were found to play a critical role in GVL production. A promising GVL yield of 98.3 mol% with a highest GVL formation rate at 5239.4 mu mol g(cat)(-1) h(-1) was obtained in isopropanol at 433 K over zirconium oxide derived from zirconyl nitrate. The recycling experiments revealed that the zirconium oxide catalyst derived from zirconyl nitrate presented relatively satisfied performance and stability.
关键词	gamma-Valerolactone Hydrogen Donors Zirconium Oxide Zirconyl Nitrate
DOI	10.1166/jbmb.2017.1717
关键词[WOS]	MEERWEIN-PONNDORF-VERLEY ; BIOMASS ; CONVERSION ; ACID ; EFFICIENT ; ESTERS ; REDUCTIONS
收录类别	SCI
语种	英语
资助项目	Natural Science Foundation of Guangdong Province, China[2014A030310386] ; Natural Science Foundation of Guangdong Province, China[2016A030313173] ; Natural Science Foundation of Guangdong Province, China[2015A030310408] ; Science and Technology Planning Project of Guangdong Province, China[2015A040404039] ; Science and Technology Planning Project of Guangdong Province, China[2015B 090901012]
WOS研究方向	Chemistry ; Energy & Fuels ; Materials Science
项目资助者	Natural Science Foundation of Guangdong Province, China ; Science and Technology Planning Project of Guangdong Province, China
WOS类目	Chemistry, Applied ; Energy & Fuels ; Materials Science, Biomaterials
WOS记录号	WOS:000430408000002
出版者	AMER SCIENTIFIC PUBLISHERS
引用统计	被引频次：6[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/23181
专题	中国科学院广州能源研究所
通讯作者	Zhang, Jun
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Dong, Kaijun,Zhang, Jun,Luo, Weimin,et al. Catalytic Transfer Hydrogenation of Ethyl Levulinate into gamma-Valerolactone Over Zirconium Oxide Derived from Zirconyl Nitrate[J]. JOURNAL OF BIOBASED MATERIALS AND BIOENERGY,2017,11(6):543-552.
APA	Dong, Kaijun,Zhang, Jun,Luo, Weimin,Su, Lin,&Huang, Zhilin.(2017).Catalytic Transfer Hydrogenation of Ethyl Levulinate into gamma-Valerolactone Over Zirconium Oxide Derived from Zirconyl Nitrate.JOURNAL OF BIOBASED MATERIALS AND BIOENERGY,11(6),543-552.
MLA	Dong, Kaijun,et al."Catalytic Transfer Hydrogenation of Ethyl Levulinate into gamma-Valerolactone Over Zirconium Oxide Derived from Zirconyl Nitrate".JOURNAL OF BIOBASED MATERIALS AND BIOENERGY 11.6(2017):543-552.