Selective Hydrogenation of Furfural to Furfuryl Alcohol over Acid Activated Attapulgite-Supported NiCoB Amorphous Alloy Catalyst

doi:10.1021/acs.iecr.7b03699

GIEC OpenIR

	Selective Hydrogenation of Furfural to Furfuryl Alcohol over Acid Activated Attapulgite-Supported NiCoB Amorphous Alloy Catalyst
	Guo, Haijun 1,2,3,4,5; Zhang, Hairong 2,3,4,5; Zhang, Liquan 2,3,4,5,6; Wang, Can 2,3,4,5; Peng, Fen 2,3,4,5; Huang, Qianlin 2,3,4,5,6; Xiong, Lian2,3,4,5 ; Huang, Chao 2,3,4,5; Ouyang, Xinping 1; Chen, Xinde2,3,4,5 ; Qiu, Xueqing 1
	2018-01-17
发表期刊	INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN	0888-5885
卷号	57 期号:2 页码:498-511
通讯作者	Ouyang, Xinping(ceouyang@scut.edu.cn) ; Chen, Xinde(cxd_cxd@hotmail.com)
摘要	Acid-activated attapulgite (H+-ATP)-supported NiCoB amorphous alloy catalysts were applied to the selective hydrogenation of furfural (FUR) to furfuryl alcohol (FA). The reduction process between metallic ions impregnated in/on H+-ATP and BH4- is important to modify the textural properties of catalyst, because of the secondary activation of Er-ATP. The enhancement of interaction between H+-ATP and NiCoB particles promotes the dispersion of NiCoB amorphous alloy. Under the optimal conditions (140 degrees C, 3 MPa H-2, 800 rpm, 3.8 wt % of NiCoB active component with respect to FUR), FUR conversion of 91.3%, and FA selectivity of 82.0% were achieved over the best catalyst (20%NiCoB/H+-ATP). Moreover, the catalyst was recycled six times and showed an increase of 3.9% in FUR conversion and 8.2% in FA selectivity, which might be due to the newly generated Co-Ni alloy active site. The low-cost nature of H+-ATP makes the supported NiCoB catalyst a potential catalyst for the industrial production of FA.
DOI	10.1021/acs.iecr.7b03699
关键词[WOS]	LIQUID-PHASE HYDROGENATION ; NI-B ; NIB/SIO2 CATALYST ; ROOM-TEMPERATURE ; RECENT PROGRESS ; CU-CATALYSTS ; CO ; PALYGORSKITE ; CONVERSION ; BIOMASS
收录类别	SCI
语种	英语
资助项目	project of National Natural Science Foundation of China[21406229] ; Project of Jiangsu Province Science and Technology[BE2014101] ; project of Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development[Y709jh1001] ; Science and Technology Program of Guangzhou, China[201707010240]
WOS研究方向	Engineering
项目资助者	project of National Natural Science Foundation of China ; Project of Jiangsu Province Science and Technology ; project of Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development ; Science and Technology Program of Guangzhou, China
WOS类目	Engineering, Chemical
WOS记录号	WOS:000423140100008
出版者	AMER CHEMICAL SOC
引用统计	被引频次：51[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/22902
专题	中国科学院广州能源研究所
通讯作者	Ouyang, Xinping; Chen, Xinde
作者单位	1.South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 5.Chinese Acad Sci, Guangzhou Inst Energy Convers, R&D Ctr Xuyi Attapulgite Appl Technol, Xuyi 211700, Peoples R China 6.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Guo, Haijun,Zhang, Hairong,Zhang, Liquan,et al. Selective Hydrogenation of Furfural to Furfuryl Alcohol over Acid Activated Attapulgite-Supported NiCoB Amorphous Alloy Catalyst[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2018,57(2):498-511.
APA	Guo, Haijun.,Zhang, Hairong.,Zhang, Liquan.,Wang, Can.,Peng, Fen.,...&Qiu, Xueqing.(2018).Selective Hydrogenation of Furfural to Furfuryl Alcohol over Acid Activated Attapulgite-Supported NiCoB Amorphous Alloy Catalyst.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,57(2),498-511.
MLA	Guo, Haijun,et al."Selective Hydrogenation of Furfural to Furfuryl Alcohol over Acid Activated Attapulgite-Supported NiCoB Amorphous Alloy Catalyst".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 57.2(2018):498-511.