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Facile synthesis of 3D binder-free N-doped carbon nanonet derived from silkworm cocoon for Li-O-2 battery
Jing, Shengyu1; Zhang, Maoshen1; Liang, Huagen2; Shen, Baolong2; Yin, Shibin3; Yang, Xu4
2018-03-01
发表期刊JOURNAL OF MATERIALS SCIENCE
ISSN0022-2461
卷号53期号:6页码:4395-4405
通讯作者Liang, Huagen(lhg654@gmail.com) ; Yang, Xu(yangxu@ms.giec.ac.cn)
摘要Rechargeable nonaqueous lithium-O-2 batteries are considered as the most promising energy storage system for electric vehicles due to their extremely high energy density. However, the inefficient O-2 diffusion, large overpotential and unwanted side reaction still restrict their specific capacity and cycle performance. This work presents a facile method to prepare a novel 3D binder-free N-doped carbon nanonet by using an economical, green and sustainable biomass-silkworm cocoon as the precursor. Li-O-2 batteries with this N-doped carbon nanonet as the cathode delivered a superior specific capacity and excellent cycling stability, which attributable to the 3D porous and through structure, high specific surface area, the enhanced catalytic activity of ORR/OER arising from the incorporation of N, and the absence of binders in the electrode. Therefore, by taking advantages of the unique structure and morphology of biomass, the low-cost and green 3D binder-free N-doped carbon materials are a feasible approach for the preparation of high-performance cathode for Li-O-2 battery.
DOI10.1007/s10853-017-1818-7
关键词[WOS]LITHIUM-OXYGEN BATTERIES ; HIERARCHICALLY POROUS CARBON ; AIR ELECTRODE ; GRAPHENE ; CATHODE ; ELECTROCATALYSTS ; REDUCTION ; NANOTUBES ; ARCHITECTURES ; PERFORMANCE
收录类别SCI
语种英语
资助项目Fundamental Research Funds for the Central Universities[2014ZDPY20]
WOS研究方向Materials Science
项目资助者Fundamental Research Funds for the Central Universities
WOS类目Materials Science, Multidisciplinary
WOS记录号WOS:000418294200039
出版者SPRINGER
引用统计
被引频次:15[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/22758
专题中国科学院广州能源研究所
通讯作者Liang, Huagen; Yang, Xu
作者单位1.China Univ Min & Technol, Sch Informat & Control Engn, Xuzhou 221116, Jiangsu, Peoples R China
2.China Univ Min & Technol, Low Carbon Energy Inst, Sch Mat Sci & Engn, Xuzhou 221116, Jiangsu, Peoples R China
3.Guangxi Univ, Collaborat Innovat Ctr Renewable Energy Mat CICRE, Nanning 530004, Peoples R China
4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式
GB/T 7714
Jing, Shengyu,Zhang, Maoshen,Liang, Huagen,et al. Facile synthesis of 3D binder-free N-doped carbon nanonet derived from silkworm cocoon for Li-O-2 battery[J]. JOURNAL OF MATERIALS SCIENCE,2018,53(6):4395-4405.
APA Jing, Shengyu,Zhang, Maoshen,Liang, Huagen,Shen, Baolong,Yin, Shibin,&Yang, Xu.(2018).Facile synthesis of 3D binder-free N-doped carbon nanonet derived from silkworm cocoon for Li-O-2 battery.JOURNAL OF MATERIALS SCIENCE,53(6),4395-4405.
MLA Jing, Shengyu,et al."Facile synthesis of 3D binder-free N-doped carbon nanonet derived from silkworm cocoon for Li-O-2 battery".JOURNAL OF MATERIALS SCIENCE 53.6(2018):4395-4405.
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