Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Catalytic conversion of carbohydrates into 5-hydroxymethyl furfural over sulfonated hyper-cross-linked polymer in DMSO | |
Dong, Kaijun1,2,3 ; Zhang, Jun1,2,3; Luo, Weimin1,2,3; Su, Lin1,2,3; Huang, Zhilin1,2,3,4
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| 2018-02-15 | |
| Source Publication | CHEMICAL ENGINEERING JOURNAL
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| ISSN | 1385-8947 |
| Volume | 334Pages:1055-1064 |
| Corresponding Author | Zhang, Jun(zhangjun@ms.giec.ac.cn) |
| Abstract | An acid functionalized porous organic hyper-cross-linked polymer (HCP) derived from benzene monomer was prepared for catalytic dehydration of carbohydrates into 5-hydroxymethyl furfural (HMF) in a DMSO solvent. Systematic characterizations of the HCP catalysts including essential structural properties, sulfur content and acid amount, were identified by XRD, XPS, FESEM, Raman, NH3-TPD, TGA, nitrogen physisorption and elemental analysis. Optimization of reaction parameters such as acid amount, solvent, substrate type, temperature and catalyst dosage, and comparison with reported solid acids were systematically investigated. The results showed that sulfonated HCP materials were highly active in fructose dehydration, which could afford a highest HMF yield of 96.7% at almost 100% fructose conversion in 30 min. Furthermore, the catalyst presented satisfied performance and stability during recycling tests. More importantly, the sulfonated HCP catalysts also exhibited promising activity in hydrolytic reaction, esterification and transesterification for platform chemicals production in biomass transformation. |
| Keyword | Hyper-cross-linked polymer Carbohydrates Dehydration 5-Hydroxymethyl furfural |
| DOI | 10.1016/j.cej.2017.10.092 |
| WOS Keyword | SOLID ACID CATALYSTS ; ION-EXCHANGE-RESIN ; D-FRUCTOSE ; SELECTIVE CONVERSION ; BIODIESEL PRODUCTION ; MESOPOROUS SILICA ; LEVULINIC ACID ; DEHYDRATION ; GLUCOSE ; WATER |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Natural Science Foundation of Guangdong Province, China[2014A030310386] ; Natural Science Foundation of Guangdong Province, China[2016A030313173] ; Science and Technology Planning Project of Guangdong Province, China[2015A040404039] ; Science and Technology Planning Project of Guangdong Province, China[2015B090901012] |
| WOS Research Area | Engineering |
| Funding Organization | Natural Science Foundation of Guangdong Province, China ; Science and Technology Planning Project of Guangdong Province, China |
| WOS Subject | Engineering, Environmental ; Engineering, Chemical |
| WOS ID | WOS:000418533400104 |
| Publisher | ELSEVIER SCIENCE SA |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/22755 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Zhang, Jun |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Dong, Kaijun,Zhang, Jun,Luo, Weimin,et al. Catalytic conversion of carbohydrates into 5-hydroxymethyl furfural over sulfonated hyper-cross-linked polymer in DMSO[J]. CHEMICAL ENGINEERING JOURNAL,2018,334:1055-1064. |
| APA | Dong, Kaijun,Zhang, Jun,Luo, Weimin,Su, Lin,&Huang, Zhilin.(2018).Catalytic conversion of carbohydrates into 5-hydroxymethyl furfural over sulfonated hyper-cross-linked polymer in DMSO.CHEMICAL ENGINEERING JOURNAL,334,1055-1064. |
| MLA | Dong, Kaijun,et al."Catalytic conversion of carbohydrates into 5-hydroxymethyl furfural over sulfonated hyper-cross-linked polymer in DMSO".CHEMICAL ENGINEERING JOURNAL 334(2018):1055-1064. |
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