Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Fabrication of MoS2 microflowers for hydrogenation of nitrobenzene | |
Li, Zhongcheng1,2; Zhang, Deliang1; Ma, Jiaojiao1; Wang, Debao1; Xie, Congxia1 | |
2018-02-15 | |
发表期刊 | MATERIALS LETTERS |
ISSN | 0167-577X |
卷号 | 213页码:350-353 |
通讯作者 | Li, Zhongcheng(zhongchengli@qust.edu.cn) ; Wang, Debao(swang@qingdaonews.com) ; Xie, Congxia(xiecongxia@126.com) |
摘要 | MoS2 microflowers with the size of 3.9-5.8 mu m in diameter, which is constructed by nanosheets, are hydrothermally synthesized using sodium diethyldithiocarbamate trihydrate as the sulfur source. Studies on the hydrothermal process reveal that the temperature plays crucial roles in determining the crystal phase of MoS2. It is found that the higher temperature favors the reduction of Mo (VI) to Mo (IV). The obtained MoS2 microflowers are highly active and selective for hydrogenation of nitrobenzene into aniline. Compared with commercial MoS2, the higher percentage of coordinative unsaturated Mo sites on MoS2 microflowers offer a relatively higher catalytic activity. (c) 2017 Elsevier B.V. All rights reserved. |
关键词 | MoS2 microflowers Coordinative unsaturated Mo sites Nitrobenzene hydrogenation Functional Microstructure |
DOI | 10.1016/j.matlet.2017.11.042 |
关键词[WOS] | TEMPERATURE-PROGRAMMED REDUCTION ; NITROARENES ; HYDRODESULFURIZATION ; NANOPARTICLES ; CATALYSTS |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Natural Science Foundation of China[21503117] ; National Natural Science Foundation of China[31270615] ; project of Shandong Province Higher Educational Science and Technology Program[J16LC16] ; Key Laboratory of Renewable Energy, Chinese Academy of Sciences[Y607k81001] ; Natural Science Foundation of Shandong Province[ZR2017MB034] |
WOS研究方向 | Materials Science ; Physics |
项目资助者 | National Natural Science Foundation of China ; project of Shandong Province Higher Educational Science and Technology Program ; Key Laboratory of Renewable Energy, Chinese Academy of Sciences ; Natural Science Foundation of Shandong Province |
WOS类目 | Materials Science, Multidisciplinary ; Physics, Applied |
WOS记录号 | WOS:000419049300088 |
出版者 | ELSEVIER SCIENCE BV |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/22559 |
专题 | 中国科学院广州能源研究所 |
通讯作者 | Li, Zhongcheng; Wang, Debao; Xie, Congxia |
作者单位 | 1.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, State Key Lab Base Ecochem Engn, Qingdao 266042, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
第一作者单位 | 中国科学院广州能源研究所 |
推荐引用方式 GB/T 7714 | Li, Zhongcheng,Zhang, Deliang,Ma, Jiaojiao,et al. Fabrication of MoS2 microflowers for hydrogenation of nitrobenzene[J]. MATERIALS LETTERS,2018,213:350-353. |
APA | Li, Zhongcheng,Zhang, Deliang,Ma, Jiaojiao,Wang, Debao,&Xie, Congxia.(2018).Fabrication of MoS2 microflowers for hydrogenation of nitrobenzene.MATERIALS LETTERS,213,350-353. |
MLA | Li, Zhongcheng,et al."Fabrication of MoS2 microflowers for hydrogenation of nitrobenzene".MATERIALS LETTERS 213(2018):350-353. |
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