sorbitolhydrogenolysistoglycolsoverbaisicadditivepromotednibasedcatalysts

GIEC OpenIR

	sorbitolhydrogenolysistoglycolsoverbaisicadditivepromotednibasedcatalysts
	Cao Xiaofeng 1; Zhang Qi2 ; Jiang Dong 1; Liu Qiying2 ; Ma Longlong2 ; Wang Tiejun2 ; Li Debao 1
	2015
发表期刊	chinesejournalofchemicalphysics
ISSN	1674-0068
卷号	000 期号:003 页码:338
摘要	A series of Ni based catalysts with different supports and basic additives were prepared by sequential impregnation method. The catalysts were characterized by XRD, BET, H2-TPR and CO2-TPD techniques. It was found that the introduction of basic additives enhanced the basicities of catalyats and promoted the dispersities of Ni particles by strong interaction between Ni2＋ and basic additives. Among the Ni based catalysts, 10%Ni/10%La203/ZrO2 showed the superior performance in sorbitol hydrogenolysis. The synergistic effect of Ni and La203 was proven to play an essential role in selective synthesis of EG and 1,2-PG. In the optimal reaction condition, the catalyst presented 100% sorbitol conversion and over 48% glycols （EG and 1,2-PG） yield. The kinetics study of polyols （sorbitol, xylitol and glycerol） hydrogenolysis showed that polyols with more hydroxyl number have higher activity and products distribution was final results of kinetic balance, which could give us some inspiration abeut how to change the products selectivity.
语种	英语
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/21055
专题	中国科学院广州能源研究所
作者单位	1.中国科学院山西煤炭化学研究所 2.中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Cao Xiaofeng,Zhang Qi,Jiang Dong,et al. sorbitolhydrogenolysistoglycolsoverbaisicadditivepromotednibasedcatalysts[J]. chinesejournalofchemicalphysics,2015,000(003):338.
APA	Cao Xiaofeng.,Zhang Qi.,Jiang Dong.,Liu Qiying.,Ma Longlong.,...&Li Debao.(2015).sorbitolhydrogenolysistoglycolsoverbaisicadditivepromotednibasedcatalysts.chinesejournalofchemicalphysics,000(003),338.
MLA	Cao Xiaofeng,et al."sorbitolhydrogenolysistoglycolsoverbaisicadditivepromotednibasedcatalysts".chinesejournalofchemicalphysics 000.003(2015):338.