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Co/SiO_2催化剂上模拟生物质合成气F-T合成的实验研究
覃欣欣1; 王铁军2; 李宇萍1; 吴创之2; 马隆龙2; 李海滨2
2010
Source Publication太阳能学报
ISSN0254-0096
Volume000Issue:006Pages:671
Abstract比较了工业合成气(A)(H2:CO:N2=64:32:4,vol%)和生物质合成气(B)(H2:CO:CO2:N2=45:45:7:3,vol%)在Co/SiO2催化剂上F-T合成的反应性能.在T=513K,P=2.0MPa,GHSV=1000h-1的条件下,气体(A)和气体(B)的(H2+CO)转化率X(H2+co)和CH4选择性SCH4分别为95.54%、41.24%和17.19%、12.25%.在反应产物的分布上,两种气体的G5+烃选择性SC5+分别为67.46%、80.62%,气体(B)的产物向高碳数烃类迁移.气体(B)100h稳定性实验表明:24h后反应活性和液态烃类选择性基本稳定,XCO和G5+收率平均值分别为29.13%、131.30g·m-3(syngas).与工业合成气相比,生物质合成气液态烃类选择性高.
Language英语
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/20440
Collection中国科学院广州能源研究所
Affiliation1.中国科学院大学
2.中国科学院广州能源研究所
Recommended Citation
GB/T 7714
覃欣欣,王铁军,李宇萍,等. Co/SiO_2催化剂上模拟生物质合成气F-T合成的实验研究[J]. 太阳能学报,2010,000(006):671.
APA 覃欣欣,王铁军,李宇萍,吴创之,马隆龙,&李海滨.(2010).Co/SiO_2催化剂上模拟生物质合成气F-T合成的实验研究.太阳能学报,000(006),671.
MLA 覃欣欣,et al."Co/SiO_2催化剂上模拟生物质合成气F-T合成的实验研究".太阳能学报 000.006(2010):671.
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