doubleiipasecatalyzedsynthesisofkojicdipalmitateinorganicsolvents

GIEC OpenIR

	doubleiipasecatalyzedsynthesisofkojicdipalmitateinorganicsolvents
	Wang Zhiyuan; Luo Wen; Fu Junying; Li Zhibing; Wang Zhongming; Lu Pengmei
	2017
发表期刊	chemicalresearchinchineseuniversities
ISSN	1005-9040
卷号	33 期号:6 页码:903
摘要	Kojic dipalmitate(KDP) was synthesized by the way of esterification of palmitic and kojic acids in organic solvent, with double-lipase as the biocatalyst. Four commercially available lipases(Amano PS, Novozym 435, Lipozyme TL IM and Lipozyme RM IM) were used to group six double-lipase combinations. These combinations were studied and Amano PS-Novozym 435 was found to have the best efficiency and was selected for optimizing the reaction conditions. The optimal reaction conditions were as follows. The mass ratio of Amano PS to Novozyme 435 was 1:1.5, with stirring speed of 500 r/min, substrates molar ratio of 1:2, 50 0C, 5%(mass fraction) catalyst dosage of kojic acid quantity and using acetone as co-solvent. Under these conditions, the diesterification of C5 and C7 hy-droxyl groups of kojic acid molecule could be well catalyzed by double-lipase and realize a high KDP yield of 85%.
语种	英语
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/20260
专题	中国科学院广州能源研究所
作者单位	中国科学院广州能源研究所
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Wang Zhiyuan,Luo Wen,Fu Junying,et al. doubleiipasecatalyzedsynthesisofkojicdipalmitateinorganicsolvents[J]. chemicalresearchinchineseuniversities,2017,33(6):903.
APA	Wang Zhiyuan,Luo Wen,Fu Junying,Li Zhibing,Wang Zhongming,&Lu Pengmei.(2017).doubleiipasecatalyzedsynthesisofkojicdipalmitateinorganicsolvents.chemicalresearchinchineseuniversities,33(6),903.
MLA	Wang Zhiyuan,et al."doubleiipasecatalyzedsynthesisofkojicdipalmitateinorganicsolvents".chemicalresearchinchineseuniversities 33.6(2017):903.