synthesisofthreedimensionallyorderedmacroporouslafeo3perovskitesandtheirperformanceforchemicalloopingreformingofmethane

GIEC OpenIR

	synthesisofthreedimensionallyorderedmacroporouslafeo3perovskitesandtheirperformanceforchemicalloopingreformingofmethane
	He Fang; Zhao Kun; Huang Zhen; Li Xinai; Wei Guoqiang; Li Haibin
	2013
发表期刊	催化学报
ISSN	1872-2067
卷号	34 期号:6 页码:1242
摘要	Three-dimensionally ordered macroporous (3DOM) LaFeO 3 perovskite-type oxides were synthesized using a polystyrene colloidal crystal templating method. The obtained 3DOM LaFeO 3 was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR). The reactivity of the perovskite-type oxides was evaluated using temperature-programmed reduction and multicyclic redox reactions by exposing them to an alternating methane and air atmosphere. The methane oxidation performance of the oxides was investigated in a fixed-bed reactor. The effect of the self-assembly method on the structure of the polystyrene template was also studied. A vertical deposition method yielded a more uniform and orderly polystyrene template than those obtained by centrifugation and evaporation techniques. The solvent and concentration of the precursor solution were the major factors to affect the prepared 3DOM perovskite. SEM analysis showed that samples synthesized with ethanol precursor solvent exhibited a better 3DOM structure than those produced with ethylene glycol, and that 1.0 mol 3 was pure crystalline perovskite. Two kinds of oxygen species were found to exist on the 3DOM perovskites: surface adsorbed oxygen and bulk lattice oxygen. The surface oxygen contributed to the complete oxidization of methane to CO 2 and H 2 O because of its higher reactivity, while the bulk lattice oxygen tended towards partial methane oxidation to H 2 and CO. The available oxygen in the 3DOM LaFeO 3 was higher than that of the same mass of non-3DOM LaFeO 3 during the partial oxidation of methane. Methane was partially oxidized into syngas with a H 2 2
语种	英语
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/19969
专题	中国科学院广州能源研究所
作者单位	中国科学院广州能源研究所
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	He Fang,Zhao Kun,Huang Zhen,et al. synthesisofthreedimensionallyorderedmacroporouslafeo3perovskitesandtheirperformanceforchemicalloopingreformingofmethane[J]. 催化学报,2013,34(6):1242.
APA	He Fang,Zhao Kun,Huang Zhen,Li Xinai,Wei Guoqiang,&Li Haibin.(2013).synthesisofthreedimensionallyorderedmacroporouslafeo3perovskitesandtheirperformanceforchemicalloopingreformingofmethane.催化学报,34(6),1242.
MLA	He Fang,et al."synthesisofthreedimensionallyorderedmacroporouslafeo3perovskitesandtheirperformanceforchemicalloopingreformingofmethane".催化学报 34.6(2013):1242.