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Hydrophilic substance assisted low temperature LiOH center dot H2O based composite thermochemical materials for thermal energy storage
Li, Shijie1,2; Huang, Hongyu1; Yang, Xixian1; Bai, Yu1; Li, Jun3; Kobayashi, Noriyuki3; Kubota, Mitsuhiro3
2018-01-05
发表期刊APPLIED THERMAL ENGINEERING
ISSN1359-4311
卷号128页码:706-711
摘要Lithium hydroxide monohydrate was modified by impregnation method with hygroscopic materials, such as polyethylene glycol (PEG), lithium chloride (LiCl), 13X-zeolite and NaY-zeolite. The lithium hydroxide monohydrate particles were well dispersed into nanoscale as composed with 13X-zeolite and NaY-zeolite. These composite materials exhibited obviously improved heat storage capacity and higher hydration rate than pure lithium hydroxide monohydrate, and the introduction of hygroscopic materials leads to greatly decreasing of apparent activation energy for the thermochemical reaction process. It is probably due to that hydrophilic materials provide efficient hygroscopic reaction interface and also show catalytic effect to the hydration reaction. Among these thermochemical materials, LiOH center dot H2O/13X-zeolite showed the lowest apparent activation energy (21.5 kj/mol) and the highest heat storage density (1949 kJ/kg), which is 2.9 times higher than the pure lithium hydroxide after the same hydration time. (C) 2017 Elsevier Ltd. All rights reserved.
文章类型Article
关键词Hygroscopic Materials Energy Storage And Conversion Lithium Hydroxide Monohydrate Thermochemical Materials Nanoparticles
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1016/j.applthermaleng.2017.09.050
研究领域[WOS]Thermodynamics ; Energy & Fuels ; Engineering ; Mechanics
关键词[WOS]CHEMICAL HEAT-STORAGE ; MAGNESIUM-HYDROXIDE ; PUMP ; ENHANCEMENT ; SURFACE
收录类别SCI
语种英语
项目资助者National Science Foundation of China(51406209 ; National Science Foundation of China(51406209 ; National Science Foundation of China(51406209 ; National Science Foundation of China(51406209 ; Science and Technology Planning Project of Guangdong Province, China(2016A050502040) ; Science and Technology Planning Project of Guangdong Province, China(2016A050502040) ; Science and Technology Planning Project of Guangdong Province, China(2016A050502040) ; Science and Technology Planning Project of Guangdong Province, China(2016A050502040) ; 51541609) ; 51541609) ; 51541609) ; 51541609) ; National Science Foundation of China(51406209 ; National Science Foundation of China(51406209 ; National Science Foundation of China(51406209 ; National Science Foundation of China(51406209 ; Science and Technology Planning Project of Guangdong Province, China(2016A050502040) ; Science and Technology Planning Project of Guangdong Province, China(2016A050502040) ; Science and Technology Planning Project of Guangdong Province, China(2016A050502040) ; Science and Technology Planning Project of Guangdong Province, China(2016A050502040) ; 51541609) ; 51541609) ; 51541609) ; 51541609)
WOS类目Thermodynamics ; Energy & Fuels ; Engineering, Mechanical ; Mechanics
WOS记录号WOS:000414884700068
出版者PERGAMON-ELSEVIER SCIENCE LTD
引用统计
被引频次:43[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/16483
专题中国科学院广州能源研究所
通讯作者Huang, Hongyu; Yang, Xixian
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Prov Key Lab New & Renewable Energy Res, Key Lab Renewable Energy, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Nagoya Univ, Chikusa Ku, Furo Cho, Nagoya, Aichi 4648603, Japan
第一作者单位中国科学院广州能源研究所
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Li, Shijie,Huang, Hongyu,Yang, Xixian,et al. Hydrophilic substance assisted low temperature LiOH center dot H2O based composite thermochemical materials for thermal energy storage[J]. APPLIED THERMAL ENGINEERING,2018,128:706-711.
APA Li, Shijie.,Huang, Hongyu.,Yang, Xixian.,Bai, Yu.,Li, Jun.,...&Kubota, Mitsuhiro.(2018).Hydrophilic substance assisted low temperature LiOH center dot H2O based composite thermochemical materials for thermal energy storage.APPLIED THERMAL ENGINEERING,128,706-711.
MLA Li, Shijie,et al."Hydrophilic substance assisted low temperature LiOH center dot H2O based composite thermochemical materials for thermal energy storage".APPLIED THERMAL ENGINEERING 128(2018):706-711.
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