Production of liquid fuel intermediates from furfural via aldol condensation over Lewis acid zeolite catalysts

doi:10.1039/c7cy01028a

GIEC OpenIR > 中国科学院广州能源研究所

	Production of liquid fuel intermediates from furfural via aldol condensation over Lewis acid zeolite catalysts
	Su, Mingxue 1; Li, Wenzhi 1; Zhang, Tingwei 1; Xin, HaoSheng 2; Li, Song 3; Fan, Wei 4; Ma, Longlong
	2017-08-21
发表期刊	CATALYSIS SCIENCE & TECHNOLOGY
卷号	7 期号:16 页码:3555-3561
摘要	Aldol condensation reactions between furfural and acetone can be used to produce liquid fuel intermediates. It was found that tin-containing zeolites with MFI (Sn-MFI) and BEA* (Sn-Beta) framework structures are effective for C-C bond formation via the aldol condensation reactions between furfural and acetone. Aldol condensation between furfural and acetone produced two main products, 4-(2-furyl)-3-buten-2-one (FAc) and 1,5-di-2-furanyl-1,4-pentadien-3-one (F2Ac). Although both these catalysts were active for the aldol condensation reactions, different selectivities to aldol products were observed over Sn-MFI and Sn-Beta. FAc and F2Ac were formed over the Sn-Beta catalyst with selectivities to FAc of 40% and F2Ac of 22%, respectively. In contrast, only FAc was produced over Sn-MFI. The variation in selectivity is likely due to different pore geometries of Sn-Beta and Sn-MFI, suggesting that Sn-MFI exhibits shape selectivity for aldol condensation between furfural and acetone. In addition, it was found that the addition of water to the reaction system can also affect the product selectivity, leading to the aldol product exclusively being FAc over Sn-Beta.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1039/c7cy01028a
研究领域[WOS]	Chemistry
关键词[WOS]	DROP-IN BIOFUELS ; RANGE ALKANES ; CONVERSION ; ACETONE ; BASE ; FORMALDEHYDE ; KETONES ; DIESEL ; WATER ; JET
收录类别	SCI
语种	英语
项目资助者	National Natural Science Foundation of China(51536009) ; National Key Technology R&D Program of China(2015BAD15B06) ; Science and Technological Fund of Anhui Province for Outstanding Youth(1508085J01) ; International Technology Cooperation Plan of Anhui(1503062030)
WOS类目	Chemistry, Physical
WOS记录号	WOS:000407636600016
引用统计	被引频次：61[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/16285
专题	中国科学院广州能源研究所
作者单位	1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Lab Basic Res Biomass Convers & Utilizat, Hefei 230026, Peoples R China 2.Anhui Jianzhu Univ, Inst Mat & Chem Engn, Hefei 230022, Anhui, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Massachusetts Amherst, Dept Chem Engn, 686 N Pleasant St, Amherst, MA 01003 USA
推荐引用方式 GB/T 7714	Su, Mingxue,Li, Wenzhi,Zhang, Tingwei,et al. Production of liquid fuel intermediates from furfural via aldol condensation over Lewis acid zeolite catalysts[J]. CATALYSIS SCIENCE & TECHNOLOGY,2017,7(16):3555-3561.
APA	Su, Mingxue.,Li, Wenzhi.,Zhang, Tingwei.,Xin, HaoSheng.,Li, Song.,...&Ma, Longlong.(2017).Production of liquid fuel intermediates from furfural via aldol condensation over Lewis acid zeolite catalysts.CATALYSIS SCIENCE & TECHNOLOGY,7(16),3555-3561.
MLA	Su, Mingxue,et al."Production of liquid fuel intermediates from furfural via aldol condensation over Lewis acid zeolite catalysts".CATALYSIS SCIENCE & TECHNOLOGY 7.16(2017):3555-3561.