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An Overview on Catalytic Hydrodeoxygenation of Pyrolysis Oil and Its Model Compounds
Si, Zhan1,2,3; Zhang, Xinghua2; Wang, Chenguang2; Ma, Longlong2; Dong, Renjie1,3,4
2017-06-01
Source PublicationCATALYSTS
Volume7Issue:6
AbstractPyrolysis is considered the most promising way to convert biomass to fuels. Upgrading biomass pyrolysis oil is essential to produce high quality hydrocarbon fuels. Upgrading technologies have been developed for decades, and this review focuses on the hydrodeoxygenation (HDO). In order to declare the need for upgrading, properties of pyrolysis oil are firstly analyzed, and potential analysis methods including some novel methods are proposed. The high oxygen content of bio-oil leads to its undesirable properties, such as chemical instability and a strong tendency to re-polymerize. Acidity, low heating value, high viscosity and water content are not conductive to making bio-oils useful as fuels. Therefore, fast pyrolysis oils should be refined before producing deoxygenated products. After the analysis of pyrolysis oil, the HDO process is reviewed in detail. The HDO of model compounds including phenolics monomers, dimers, furans, carboxylic acids and carbohydrates is summarized to obtain sufficient information in understanding HDO reaction networks and mechanisms. Meanwhile, investigations of model compounds also make sense for screening and designing HDO catalysts. Then, we review the HDO of actual pyrolysis oil with different methods including two-stage treatment, co-feeding solvents and in-situ hydrogenation. The relative merits of each method are also expounded. Finally, HDO catalysts are reviewed in order of time. After the summarization of petroleum derived sulfured catalysts and noble metal catalysts, transitional metal carbide, nitride and phosphide materials are summarized as the new trend for their low cost and high stability. After major progress is reviewed, main problems are summarized and possible solutions are raised.
SubtypeReview
KeywordBiomass Pyrolysis Oil Hydrodeoxygenation Catalysts
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.3390/catal7060169
WOS Subject ExtendedChemistry
WOS KeywordVAPOR-PHASE HYDRODEOXYGENATION ; 2-DIMENSIONAL GAS-CHROMATOGRAPHY ; TRANSITION-METAL PHOSPHIDES ; FLIGHT MASS-SPECTROMETRY ; SUPPORTED RU CATALYSTS ; BIO-OIL ; M-CRESOL ; GUAIACOL HYDRODEOXYGENATION ; PHENOL HYDRODEOXYGENATION ; PT/HBETA CATALYST
Indexed BySCI
Language英语
Funding OrganizationNSFC (Natural Science Foundation of China)(51476175 ; national basic research program of china(2013CB228105) ; Chinese Academy of Sciences "one hundred talented plan" ; Beijing Municipal Key Discipline of Biomass Engineering ; 51606205)
WOS SubjectChemistry, Physical
WOS IDWOS:000404380300003
Citation statistics
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/14163
Collection中国科学院广州能源研究所
Affiliation1.China Agr Univ, Coll Engn, Bioenergy & Environm Sci & Technol Lab, 17 Qinghua Donglu, Beijing 100083, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
3.China Agr Univ, Coll Engn, Key Lab Clean Prod & Utilizat Technol Renewable E, Minist Agr, Beijing 100083, Peoples R China
4.Natl Ctr Int Res BioEnergy Sci & Technol, Minist Sci & Technol, Beijing 100083, Peoples R China
Recommended Citation
GB/T 7714
Si, Zhan,Zhang, Xinghua,Wang, Chenguang,et al. An Overview on Catalytic Hydrodeoxygenation of Pyrolysis Oil and Its Model Compounds[J]. CATALYSTS,2017,7(6).
APA Si, Zhan,Zhang, Xinghua,Wang, Chenguang,Ma, Longlong,&Dong, Renjie.(2017).An Overview on Catalytic Hydrodeoxygenation of Pyrolysis Oil and Its Model Compounds.CATALYSTS,7(6).
MLA Si, Zhan,et al."An Overview on Catalytic Hydrodeoxygenation of Pyrolysis Oil and Its Model Compounds".CATALYSTS 7.6(2017).
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