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An improved solid-state method for synthesizing LiNi0.5Mn1.5O4 cathode material for lithium ion batteries
He, Yunlong1; Zhang, Jie1; Li, Qiu1; Hao, Yong; Yang, Jianwen1,3; Zhang, Lingzhi1,2; Wang, Chunlei3
2017-08-25
发表期刊JOURNAL OF ALLOYS AND COMPOUNDS
卷号715页码:304-310
摘要High voltage LiNi0.5Mn1.5O4 cathode material was prepared by two steps solid-state method with additive PEG dispersant. XRD, SEM, XPS and electrochemical tests have been carried out, and the results show that the PEG can promote the pyrolysis of MnO2 and limit the impurities formation. The secondary particle can also be effectively restrained in the pre-calcination of MnO2 and NiO, and the effect can be last to the final product. The capacity from Mn3+/ Mn4+ couple was reduced and the whole capacity can reach 140.7 mAh g(-1) with the retention rate of 81.33% after 100 cycles at 0.2C. Meanwhile, the product has better rate performance and surface stability than those prepared by traditional two-step solid-state method. (C) 2017 Elsevier B.V. All rights reserved.
文章类型Review
关键词Improvement Solid-state Method Lini0.5mn1.5o4 Lithium Ion Batteries
WOS标题词Science & Technology ; Physical Sciences ; Technology
资助者National Natural Science Foundation of China(51164006/21573239) ; Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials(EMFM20161105) ; CAS Key Laboratory of Renewable Energy(Y407K41001) ; Science and Technology Program of Guangxi Province in China(1298025-9) ; Special Support Program of Guangdong Province for High-Level Talents(2014TX01N014) ; National Natural Science Foundation of China(51164006/21573239) ; Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials(EMFM20161105) ; CAS Key Laboratory of Renewable Energy(Y407K41001) ; Science and Technology Program of Guangxi Province in China(1298025-9) ; Special Support Program of Guangdong Province for High-Level Talents(2014TX01N014)
DOI10.1016/j.jallcom.2017.04.293
研究领域[WOS]Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
关键词[WOS]ELECTROCHEMICAL PERFORMANCES ; SPINEL CATHODE ; LIMN1.5NI0.5O4 ; TEMPERATURE ; MECHANISM ; STRATEGY
收录类别SCI
语种英语
资助者National Natural Science Foundation of China(51164006/21573239) ; Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials(EMFM20161105) ; CAS Key Laboratory of Renewable Energy(Y407K41001) ; Science and Technology Program of Guangxi Province in China(1298025-9) ; Special Support Program of Guangdong Province for High-Level Talents(2014TX01N014) ; National Natural Science Foundation of China(51164006/21573239) ; Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials(EMFM20161105) ; CAS Key Laboratory of Renewable Energy(Y407K41001) ; Science and Technology Program of Guangxi Province in China(1298025-9) ; Special Support Program of Guangdong Province for High-Level Talents(2014TX01N014)
WOS类目Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号WOS:000402919400040
引用统计
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/14139
专题中国科学院广州能源研究所
作者单位1.Guilin Univ Technol, Coll Chem & Bioengn, Guangxi Key Lab Electrochem & Magnetochem Funct M, Guilin 541000, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
3.Florida Int Univ, Dept Mech & Mat Engn, Miami, FL 33174 USA
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He, Yunlong,Zhang, Jie,Li, Qiu,et al. An improved solid-state method for synthesizing LiNi0.5Mn1.5O4 cathode material for lithium ion batteries[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2017,715:304-310.
APA He, Yunlong.,Zhang, Jie.,Li, Qiu.,Hao, Yong.,Yang, Jianwen.,...&Wang, Chunlei.(2017).An improved solid-state method for synthesizing LiNi0.5Mn1.5O4 cathode material for lithium ion batteries.JOURNAL OF ALLOYS AND COMPOUNDS,715,304-310.
MLA He, Yunlong,et al."An improved solid-state method for synthesizing LiNi0.5Mn1.5O4 cathode material for lithium ion batteries".JOURNAL OF ALLOYS AND COMPOUNDS 715(2017):304-310.
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