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One-Pot Conversion of Carbohydrates into 5-(Hydroxymethyl)furfural using Heterogeneous Lewis-Acid and Bronsted-Acid Catalysts
Zhang, Tingwei1; Fan, Wei2; Li, Wenzhi1; Xu, Zhiping3; Xin, Haosheng4; Su, Mingxue3; Lu, Yijuan1; Ma, Longlong5
2017-05-01
Source PublicationENERGY TECHNOLOGY
Volume5Issue:5Pages:747-755
AbstractSn-beta zeolite and PTSA-POM, made from the copolymerization of p-toluenesulfonic acid (PTSA) and paraformaldehyde (POM), were used for the production of 5-(hydroxymethyl)-furfural (HMF) from glucose in an environmentally friendly solvent system including gamma-valerolactone (GVL) and H2O. The effects of reaction temperature, reaction time, solvent, and catalyst-to-reactant ratio on the production of HMF were investigated. The combination of the Bronsted acid and Lewis acid catalysts largely improved the catalytic system and resulted in the production of HMF in 60.1% yield at 140 degrees C in 30min. The presence of water in the solvent had a positive influence on the production of HMF from glucose. The combination of the two catalysts also improved the catalytic performance for the production of HMF from cellulose and corn stalk.
SubtypeArticle
KeywordCarbohydrates Cellulose Corn Stalk Heterogeneous Catalysis Sustainable Chemistry
WOS HeadingsScience & Technology ; Technology
DOI10.1002/ente.201600492
WOS Subject ExtendedEnergy & Fuels
WOS KeywordBIOMASS ENERGY CONVERSATION ; GAMMA-VALEROLACTONE ; IONIC LIQUIDS ; SN-BETA ; GLUCOSE ISOMERIZATION ; EFFICIENT CONVERSION ; LEVULINIC ACID ; AQUEOUS-MEDIA ; ACTIVE-SITES ; CORN STALK
Indexed BySCI
Language英语
Funding OrganizationNational Key Technology R&D Program of China(2015BAD15B06) ; National Basic Research Program of China(2012CB215302) ; Science and Technological Fund of Anhui Province for Outstanding Youth(1508085J01) ; International Technology Cooperation Plan of Anhui(1503062030)
WOS SubjectEnergy & Fuels
WOS IDWOS:000401237900013
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/14126
Collection中国科学院广州能源研究所
Affiliation1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, 96 Jinzhai Rd, Hefei 230026, Anhui, Peoples R China
2.Univ Massachusetts, Chem Engn Dept, Goessmann Lab 177B, 686 N Pleasant St, Amherst, MA 01003 USA
3.Univ Sci & Technol China, Dept Chem, 96 Jinzhai Rd, Anhua 230026, Anhui, Peoples R China
4.Anhui Jiangzhu Univ, Inst Mat & Chem Engn, Hefei 230022, Peoples R China
5.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Tingwei,Fan, Wei,Li, Wenzhi,et al. One-Pot Conversion of Carbohydrates into 5-(Hydroxymethyl)furfural using Heterogeneous Lewis-Acid and Bronsted-Acid Catalysts[J]. ENERGY TECHNOLOGY,2017,5(5):747-755.
APA Zhang, Tingwei.,Fan, Wei.,Li, Wenzhi.,Xu, Zhiping.,Xin, Haosheng.,...&Ma, Longlong.(2017).One-Pot Conversion of Carbohydrates into 5-(Hydroxymethyl)furfural using Heterogeneous Lewis-Acid and Bronsted-Acid Catalysts.ENERGY TECHNOLOGY,5(5),747-755.
MLA Zhang, Tingwei,et al."One-Pot Conversion of Carbohydrates into 5-(Hydroxymethyl)furfural using Heterogeneous Lewis-Acid and Bronsted-Acid Catalysts".ENERGY TECHNOLOGY 5.5(2017):747-755.
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