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A novel peat biochar supported catalyst for the transesterification reaction
Wang, Shuxiao1,2,3; Zhao, Che1,2; Shan, Rui1,2; Wang, Yazhuo1,2; Yuan, Haoran1,2,3
2017-05-01
发表期刊ENERGY CONVERSION AND MANAGEMENT
卷号139页码:89-96
摘要In the present study, the peat, as solid waste, was utilized as the support to prepare carbon solid base catalyst for biodiesel production from palm oil. The chemical and structural properties of catalysts were examined by thermogravimetric analysis (TGA), scanning electron microscope (SEM), energy dispersive spectrometer (EDS), Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), N-2 adsorptionfdesorption and the Hammett indicator method. The results indicated that 30K/PB-600 catalyst exhibited the highest catalytic activity (the maximum biodiesel yield of 98.6% was acquired) owing to its highest total basicity. Besides, the stability of the catalyst during reaction was also demonstrated. After 9 repeated use, the catalyst could still possess a rather high catalytic activity (biodiesel yield of 81%). The little deactivation of catalyst was mainly owing to K+ ions leached into reaction media. Therefore, biochar derived from peat could prove to be an appropriate material for catalyst synthesis. (C) 2017 Elsevier Ltd. All rights reserved.
文章类型Article
关键词Biochar Transesterification Carbon Solid Base Catalyst Biodiesel Peat
WOS标题词Science & Technology ; Physical Sciences ; Technology
资助者National Natural Science Funds of China(51406207) ; Youth Innovation Promotion ASsociadon, CAS, China(2014320) ; Guangdong High-level Personnel of Special Support Program(2014TQ01Z379) ; Science and Technology Planning Project of Guangdong Province, China(2015A030401059 ; Cooperation Project of Industry University-Research in Guangdong Province, China(2015B090904009) ; 2014A080802009) ; National Natural Science Funds of China(51406207) ; Youth Innovation Promotion ASsociadon, CAS, China(2014320) ; Guangdong High-level Personnel of Special Support Program(2014TQ01Z379) ; Science and Technology Planning Project of Guangdong Province, China(2015A030401059 ; Cooperation Project of Industry University-Research in Guangdong Province, China(2015B090904009) ; 2014A080802009)
DOI10.1016/j.enconman.2017.02.039
研究领域[WOS]Thermodynamics ; Energy & Fuels ; Mechanics
关键词[WOS]SOLID BASE CATALYST ; WASTE COOKING OIL ; SUSTAINABLE BIODIESEL PRODUCTION ; SOYBEAN OIL ; PALM OIL ; HETEROGENEOUS CATALYSTS ; ACTIVATED CARBON ; SUNFLOWER OIL ; ACID CATALYST ; SHELL
收录类别SCI
语种英语
资助者National Natural Science Funds of China(51406207) ; Youth Innovation Promotion ASsociadon, CAS, China(2014320) ; Guangdong High-level Personnel of Special Support Program(2014TQ01Z379) ; Science and Technology Planning Project of Guangdong Province, China(2015A030401059 ; Cooperation Project of Industry University-Research in Guangdong Province, China(2015B090904009) ; 2014A080802009) ; National Natural Science Funds of China(51406207) ; Youth Innovation Promotion ASsociadon, CAS, China(2014320) ; Guangdong High-level Personnel of Special Support Program(2014TQ01Z379) ; Science and Technology Planning Project of Guangdong Province, China(2015A030401059 ; Cooperation Project of Industry University-Research in Guangdong Province, China(2015B090904009) ; 2014A080802009)
WOS类目Thermodynamics ; Energy & Fuels ; Mechanics
WOS记录号WOS:000397683900007
引用统计
被引频次:9[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/14104
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China
3.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China
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Wang, Shuxiao,Zhao, Che,Shan, Rui,et al. A novel peat biochar supported catalyst for the transesterification reaction[J]. ENERGY CONVERSION AND MANAGEMENT,2017,139:89-96.
APA Wang, Shuxiao,Zhao, Che,Shan, Rui,Wang, Yazhuo,&Yuan, Haoran.(2017).A novel peat biochar supported catalyst for the transesterification reaction.ENERGY CONVERSION AND MANAGEMENT,139,89-96.
MLA Wang, Shuxiao,et al."A novel peat biochar supported catalyst for the transesterification reaction".ENERGY CONVERSION AND MANAGEMENT 139(2017):89-96.
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