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Synthesis of Glycerol Carbonate from Glycerol and Dimethyl Carbonate Using Ionic Liquid Catalysts
Miao, Changlin1,2,3; Fan, Pei1,2,3,4; Zhuang, Xinshu1,2,3; Wang, Zhongming1,2,3; Li, Huiwen1,2,3; Lv, Pengmei1,2,3,5; Yuan, Zhenhong1,2,3
2016-12-01
发表期刊JOURNAL OF BIOBASED MATERIALS AND BIOENERGY
卷号10期号:6页码:452-457
摘要Acidic, basic and neutral ionic liquids (ILs) were prepared by two-step method. Their IR and NMR spectra showed that their structures were in accordance with their theoretical structure. Then these ILs were used as catalysts in the Glycerol carbonate (GC) of glycerol with dimethyl carbonate (DMC). The results show that basic ILs have high catalytic activity compared with acidic or neutral ILs and inorganic basic catalysts in the reaction. Under the suitable conditions using [Bmin]lm as a catalyst led to the yield of GC reached 94%, glycerol conversion reached 96%, GC selectivity reached 97% at molar ratio of DMC to glycerol at 3: 1, mass fraction of ionic liquid 12% (omega), reaction temperature 80 degrees C and reaction time 70 min. The ionic liquid was stable, and its activity did not decrease after using for 8 times (i. e., 85% glycerol conversion and near 90% GC selectivity). The results showed that the basic ionic liquid is more ideal green catalyst in esterification reaction.
文章类型Article
关键词Ionic Liquid Dimethyl Carbonate Glycerol Glycerol Carbonate
WOS标题词Science & Technology ; Physical Sciences ; Technology
资助者State Key Program of National Nature Science Foundation of China(21506217) ; Natural Science Foundation of Guangdong Province(2016A030308004) ; State Key Program of National Nature Science Foundation of China(21506217) ; Natural Science Foundation of Guangdong Province(2016A030308004)
DOI10.1166/jbmb.2016.1625
研究领域[WOS]Chemistry ; Energy & Fuels ; Materials Science
收录类别SCI ; ISTP
语种英语
资助者State Key Program of National Nature Science Foundation of China(21506217) ; Natural Science Foundation of Guangdong Province(2016A030308004) ; State Key Program of National Nature Science Foundation of China(21506217) ; Natural Science Foundation of Guangdong Province(2016A030308004)
WOS类目Chemistry, Applied ; Energy & Fuels ; Materials Science, Biomaterials
WOS记录号WOS:000397803900009
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/14094
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
5.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan Province, Peoples R China
推荐引用方式
GB/T 7714
Miao, Changlin,Fan, Pei,Zhuang, Xinshu,et al. Synthesis of Glycerol Carbonate from Glycerol and Dimethyl Carbonate Using Ionic Liquid Catalysts[J]. JOURNAL OF BIOBASED MATERIALS AND BIOENERGY,2016,10(6):452-457.
APA Miao, Changlin.,Fan, Pei.,Zhuang, Xinshu.,Wang, Zhongming.,Li, Huiwen.,...&Yuan, Zhenhong.(2016).Synthesis of Glycerol Carbonate from Glycerol and Dimethyl Carbonate Using Ionic Liquid Catalysts.JOURNAL OF BIOBASED MATERIALS AND BIOENERGY,10(6),452-457.
MLA Miao, Changlin,et al."Synthesis of Glycerol Carbonate from Glycerol and Dimethyl Carbonate Using Ionic Liquid Catalysts".JOURNAL OF BIOBASED MATERIALS AND BIOENERGY 10.6(2016):452-457.
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