Fast Pyrolysis of Nitrogen-Rich Wood Waste Pretreated by Microwave-Assisted Glycerolysis

doi:10.1007/s12649-016-9578-1

GIEC OpenIR > 中国科学院广州能源研究所

	Fast Pyrolysis of Nitrogen-Rich Wood Waste Pretreated by Microwave-Assisted Glycerolysis
	Zheng, Anqing1,2,3 ; Zhao, Kun1,2,3 ; Zhao, Zengli1,2,3 ; Jiang, Liqun 1,2,3; Huang, Zhen 1,2,3; Wei, Guoqiang 1,2,3; Wang, Xiaobo1,2,3 ; He, Fang1,2,3 ; Li, Haibin1,2,3
	2017-03-01
发表期刊	WASTE AND BIOMASS VALORIZATION
卷号	8 期号:2 页码:349-358
摘要	The high nitrogen content in wood waste containing urea formaldehyde from furniture industry hampers its utilization as a clean fuel. Herein, microwave-assisted organosolv pretreatment of wood waste using glycerol as solvent was conducted in a commercial microwave reactor with varying temperature of 120-240 degrees C for reducing nitrogen content. The elemental analysis shows that up to 88.1 % of nitrogen and 92.9 % of alkali and alkaline earth metals in wood waste can be removed by microwave-assisted glycerolysis. The solid nuclear magnetic resonance spectrometry analysis illustrate that the urea-formaldehyde resin, lignin and hemicellulose fractions in wood waste can also be simultaneously reduced by pretreatment. Raw and pretreated wood waste was subsequently fast pyrolyzed in a semi-batch pyroprobe reactor. The experimental results demonstrate that the relative content of levoglucosan in pyrolysis vapors was significantly enhanced by pretreatment, whereas the relative content of nitrogen-containing compounds was reduced obviously. These findings provide a simple and efficient pretreatment method for reducing the formation of nitrogenous compounds during fast pyrolysis of nitrogen-rich wood waste.
文章类型	Article
关键词	Wood Waste Microwave Pretreatment Organosolv Pretreatment Nitrogen Removal Fast Pyrolysis Sugar Production
WOS标题词	Science & Technology ; Life Sciences & Biomedicine
DOI	10.1007/s12649-016-9578-1
研究领域[WOS]	Environmental Sciences & Ecology
关键词[WOS]	MELAMINE-FORMALDEHYDE RESINS ; UREA-FORMALDEHYDE ; BIO-OIL ; BIOMASS ; TORREFACTION ; TEMPERATURE ; EMISSION ; LIGNIN
收录类别	SCI
语种	英语
项目资助者	National Natural Science Foundation of China(51376186 ; Natural Science Foundation of Guangdong Province, China(2014A030313672) ; Science and Technology Planning Project of Guangdong Province, China(2014B020216004 ; 21406227) ; 2015A020215024)
WOS类目	Environmental Sciences
WOS记录号	WOS:000394351600009
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/14092
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Zheng, Anqing,Zhao, Kun,Zhao, Zengli,et al. Fast Pyrolysis of Nitrogen-Rich Wood Waste Pretreated by Microwave-Assisted Glycerolysis[J]. WASTE AND BIOMASS VALORIZATION,2017,8(2):349-358.
APA	Zheng, Anqing.,Zhao, Kun.,Zhao, Zengli.,Jiang, Liqun.,Huang, Zhen.,...&Li, Haibin.(2017).Fast Pyrolysis of Nitrogen-Rich Wood Waste Pretreated by Microwave-Assisted Glycerolysis.WASTE AND BIOMASS VALORIZATION,8(2),349-358.
MLA	Zheng, Anqing,et al."Fast Pyrolysis of Nitrogen-Rich Wood Waste Pretreated by Microwave-Assisted Glycerolysis".WASTE AND BIOMASS VALORIZATION 8.2(2017):349-358.