Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Aqueous-Phase Hydrodeoxygenation of Biomass Sugar Alcohol into Renewable Alkanes over a Carbon-Supported Ruthenium with Phosphoric Acid Catalytic System | |
Weng, Yujing1,2; Wang, Tiejun1; Qiu, Songbai1; Wang, Chenguang1; Ma, Longlong1; Zhang, Qi1; Chen, Lungang1; Li, Yuping1; Sun, Fei1; Zhang, Qian1,2 | |
2017-03-01 | |
发表期刊 | CHEMCATCHEM |
卷号 | 9期号:5页码:774-781 |
摘要 | Recently, we demonstrated the catalytic conversion of biomass hydrolysate and real biomass into renewable alkanes over a Ru/C catalyst with aqueous phosphoric acid (Ru/C+H3PO4) and we obtained a high yield of C-5/C-6 alkanes. In this study, the mechanism of sorbitol hydrodeoxygenation (HDO) into alkanes over the Ru/C+H3PO4 catalytic system was investigated by using a trickle-bed reactor. A high HDO performance was detected with a large amount of long-chain alkanes in the products. Subsequently, pre- and postcharacterization studies (N-2 adsorption, XRD, X-ray photoelectron spectroscopy, TEM, NH3 temperature-programmed desorption, H-2 temperature-programmed reduction, FTIR spectroscopy) were performed on the relevant catalysts to study the change of the catalytic active sites. Moreover, mineral acid experiments were performed to study the influence of phosphoric acid on the HDO performance. |
文章类型 | Article |
关键词 | Alcohols Alkanes Biomass Ruthenium Supported Catalysts |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1002/cctc.201601470 |
研究领域[WOS] | Chemistry |
关键词[WOS] | STABLE HETEROGENEOUS CATALYSTS ; TRANSFER HYDROGENATION ; RU/C CATALYST ; SORBITOL TRANSFORMATION ; LIGNOCELLULOSIC BIOMASS ; OXYGEN REDUCTION ; CONVERSION ; PHOSPHATE ; DEHYDRATION ; EFFICIENT |
收录类别 | SCI |
语种 | 英语 |
项目资助者 | National Natural Science Foundation of China(51476176 ; key program of Chinese Academy of Sciences(KGZD-EW-304-2) ; Guangdong province special Talent support plan(511054728068) ; 51536009) |
WOS类目 | Chemistry, Physical |
WOS记录号 | WOS:000395799000009 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/14085 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Prov Key Lab New & Renewable Energy Res, Key Lab Renewable Energy, Nengyuan Rd 2, Guangzhou 510640, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
第一作者单位 | 中国科学院广州能源研究所 |
推荐引用方式 GB/T 7714 | Weng, Yujing,Wang, Tiejun,Qiu, Songbai,et al. Aqueous-Phase Hydrodeoxygenation of Biomass Sugar Alcohol into Renewable Alkanes over a Carbon-Supported Ruthenium with Phosphoric Acid Catalytic System[J]. CHEMCATCHEM,2017,9(5):774-781. |
APA | Weng, Yujing.,Wang, Tiejun.,Qiu, Songbai.,Wang, Chenguang.,Ma, Longlong.,...&Zhang, Qian.(2017).Aqueous-Phase Hydrodeoxygenation of Biomass Sugar Alcohol into Renewable Alkanes over a Carbon-Supported Ruthenium with Phosphoric Acid Catalytic System.CHEMCATCHEM,9(5),774-781. |
MLA | Weng, Yujing,et al."Aqueous-Phase Hydrodeoxygenation of Biomass Sugar Alcohol into Renewable Alkanes over a Carbon-Supported Ruthenium with Phosphoric Acid Catalytic System".CHEMCATCHEM 9.5(2017):774-781. |
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