Conversion of Cellulose to 5-Hydroxymethylfurfural using Inorganic Acidic Catalysts in the Presence of Pressurized Water Steam

doi:10.15376/biores.12.1.1201-1215

GIEC OpenIR > 中国科学院广州能源研究所

	Conversion of Cellulose to 5-Hydroxymethylfurfural using Inorganic Acidic Catalysts in the Presence of Pressurized Water Steam
	Cai, Chiliu1,2,3,4 ; Liu, Qiying1,2,3 ; Tan, Jin 1,2,3; Wang, Tiejun1,2,3 ; Zhang, Qi1,2,3 ; Ma, Longlong1,2,3
	2017
发表期刊	BIORESOURCES
卷号	12 期号:1 页码:1201-1215
摘要	Traditionally, 5-hydroxymethylfurfural ( HMF) is produced by using a water-organic solvent medium, which inevitably increases production costs and adds subsequent separation processes. To minimize cost and/or toxic organic solvent usage, this study presents an effective pathway for producing HMF from cellulose. The process uses a fixed bed reactor with a steam stripping process in which the cellulose is converted into HMF and other products in the presence of acidic inorganic salts. In the process, the cellulose was hydrolyzed to glucose, which was followed by isomerization to fructose and fructose dehydration into HMF. The produced HMF was easily vaporized into the gas phase, which avoided its conversion into undesired byproducts. An acceptable HMF yield of 28.2 mol% was obtained using KH2PO4 as the catalyst at 270 degrees C. This technology could be used to obtain both HMF and furfural ( FF) from different lignocellulosic biomasses. This stripping technology has advantages such as the lack of organic solvents, showing an alternative and green HMF and/or FF production from lignocellulosic biomass.
文章类型	Article
关键词	Cellulose Hmf Conversion Steam Stripping Process Fixed Bed
WOS标题词	Science & Technology ; Technology
DOI	10.15376/biores.12.1.1201-1215
研究领域[WOS]	Materials Science
关键词[WOS]	LIQUID-WATER ; LEVULINIC ACID ; BIOMASS ; HYDROCARBONS ; HYDROLYSIS ; PRETREATMENT ; DEHYDRATION ; MECHANISM ; SOLVENTS ; ZEOLITE
收录类别	SCI
语种	英语
项目资助者	National Science Foundation of China(51536009 ; 51576199 ; 51376185)
WOS类目	Materials Science, Paper & Wood
WOS记录号	WOS:000397065200088
引用统计	被引频次：11[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/14076
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Cai, Chiliu,Liu, Qiying,Tan, Jin,et al. Conversion of Cellulose to 5-Hydroxymethylfurfural using Inorganic Acidic Catalysts in the Presence of Pressurized Water Steam[J]. BIORESOURCES,2017,12(1):1201-1215.
APA	Cai, Chiliu,Liu, Qiying,Tan, Jin,Wang, Tiejun,Zhang, Qi,&Ma, Longlong.(2017).Conversion of Cellulose to 5-Hydroxymethylfurfural using Inorganic Acidic Catalysts in the Presence of Pressurized Water Steam.BIORESOURCES,12(1),1201-1215.
MLA	Cai, Chiliu,et al."Conversion of Cellulose to 5-Hydroxymethylfurfural using Inorganic Acidic Catalysts in the Presence of Pressurized Water Steam".BIORESOURCES 12.1(2017):1201-1215.