Effect of Ru Particle Size on Hydrogenation/Decarbonylation of Propanoic Acid Over Supported Ru Catalysts in Aqueous Phase

doi:10.1007/s10562-016-1877-4

GIEC OpenIR > 中国科学院广州能源研究所

	Effect of Ru Particle Size on Hydrogenation/Decarbonylation of Propanoic Acid Over Supported Ru Catalysts in Aqueous Phase
	Chen, Lungang; Li, Yuping; Zhang, Xinghua; Zhang, Qi; Wang, Tiejun; Ma, Longlong
	2017
发表期刊	CATALYSIS LETTERS
卷号	147 期号:1 页码:29-38
摘要	The aqueous-phase hydrogenation of propanoic acid was performed over the Ru/ZrO2 and Ru/Al2O3 catalysts with different Ru loading. Combined with multiple characterization techniques, such as H-2-TPR, XRD, CO-FTIR, and DRIFTS of propanoic acid, the effect of Ru loading on the decarbonylation/hydrogenation of propanoic acid was investigated. Although hydrogenation/decarbonylation of carboxylic acids were strongly affected by the nature of supports, the increase of metal loading can cause the larger Ru particles and more bare Ru metal sites, which can facilitate the C-C bond cleavage reaction derived from the decarbonylation of propanoyl species over Ru metal sites.
文章类型	Article
关键词	Ru Loading Carboxylic Acid Hydrogenation Decarbonylation C-c Cleavage
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1007/s10562-016-1877-4
研究领域[WOS]	Chemistry
关键词[WOS]	ACETIC-ACID ; CO ADSORPTION ; LACTIC-ACID ; RUTHENIUM CATALYSTS ; SUCCINIC ACID ; HYDROGENATION ; BIOMASS ; HYDROGENOLYSIS ; REDUCTION ; CHEMICALS
收录类别	SCI
语种	英语
项目资助者	National Natural Science Foundation of China(51306189) ; Science and Technology Program of Guangdong Province(2014A010106022) ; Comprehensive Strategic Cooperation Project of Guangdong Province ; Chinese Academy of Sciences(2012B090400042) ; China-EU SMEs Cooperation Fund for Energy Conservation Research Project(SQ2013ZOB000002)
WOS类目	Chemistry, Physical
WOS记录号	WOS:000394139200004
引用统计	被引频次：11[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/14047
专题	中国科学院广州能源研究所
作者单位	Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Chen, Lungang,Li, Yuping,Zhang, Xinghua,et al. Effect of Ru Particle Size on Hydrogenation/Decarbonylation of Propanoic Acid Over Supported Ru Catalysts in Aqueous Phase[J]. CATALYSIS LETTERS,2017,147(1):29-38.
APA	Chen, Lungang,Li, Yuping,Zhang, Xinghua,Zhang, Qi,Wang, Tiejun,&Ma, Longlong.(2017).Effect of Ru Particle Size on Hydrogenation/Decarbonylation of Propanoic Acid Over Supported Ru Catalysts in Aqueous Phase.CATALYSIS LETTERS,147(1),29-38.
MLA	Chen, Lungang,et al."Effect of Ru Particle Size on Hydrogenation/Decarbonylation of Propanoic Acid Over Supported Ru Catalysts in Aqueous Phase".CATALYSIS LETTERS 147.1(2017):29-38.