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Catalytic Conversion of Biomass-derived Carbohydrates into 5-Hydroxymethylfurfural using a Strong Solid Acid Catalyst in Aqueous gamma-Valerolactone
Li, Wenzhi1; Xu, Zhiping2; Zhang, Tingwei1; Li, Guojun2; Jameel, Hasan3; Chang, Hou-min3; Ma, Longlong4
2016-08-01
发表期刊BIORESOURCES
卷号11期号:3页码:5839-5853
摘要Selective conversion of biomass-derived carbohydrates into 5-hydroxy-methylfurfural (HMF) is of great significance for biomass conversion. In this study, a novel solid Bronsted acid was prepared simply by the copolymerization of paraformaldehyde and p-toluenesulfonic acid and then used to catalyze the conversion of various carbohydrates into HMF in.-valerolactone-water (GVL/H2O) reaction medium for the first time. The catalyst exhibited strong acidity, good water resistance, and high thermal stability. The present work focuses on the effects of various reaction parameters, including reaction temperature, time, water concentration, solvent, fructose level, and catalyst loading, on fructose dehydration. The catalyst exhibited excellent catalytic performance for HMF production from fructose in GVL and furnished a high HMF yield of 78.1% at 130 degrees C in 30 min. The recycling experiments suggested that the solid acid catalyst could be recycled at least seven times without a noticeable decrease in the catalytic activity. In addition, an attempt to study the one-step conversion of sucrose, glucose, and cellulose into HMF and furfural was performed using the same catalytic system.
文章类型Article
关键词Fructose 5-hydroxymethylfurfural Dehydration Gamma-valerolactone Ptsa-pom Catalyst
WOS标题词Science & Technology ; Technology
资助者Science and Technological Fund of Anhui Province for Outstanding Youth(1508085J01) ; National Basic Research Program of China(2012CB215302) ; National Key Technologies RD Program(2015BAD15B06) ; Key Programs of the Chinese Academy of Sciences(KGZD-EW-304-2) ; Science and Technological Fund of Anhui Province for Outstanding Youth(1508085J01) ; National Basic Research Program of China(2012CB215302) ; National Key Technologies RD Program(2015BAD15B06) ; Key Programs of the Chinese Academy of Sciences(KGZD-EW-304-2)
DOI10.15376/biores.11.3.5839-5853
研究领域[WOS]Materials Science
关键词[WOS]LIGNOCELLULOSIC BIOMASS ; SUSTAINABLE PLATFORM ; ORGANIC-SOLVENT ; IONIC LIQUIDS ; FRUCTOSE ; GLUCOSE ; DEHYDRATION ; EFFICIENT ; CELLULOSE ; HMF
收录类别SCI
语种英语
资助者Science and Technological Fund of Anhui Province for Outstanding Youth(1508085J01) ; National Basic Research Program of China(2012CB215302) ; National Key Technologies RD Program(2015BAD15B06) ; Key Programs of the Chinese Academy of Sciences(KGZD-EW-304-2) ; Science and Technological Fund of Anhui Province for Outstanding Youth(1508085J01) ; National Basic Research Program of China(2012CB215302) ; National Key Technologies RD Program(2015BAD15B06) ; Key Programs of the Chinese Academy of Sciences(KGZD-EW-304-2)
WOS类目Materials Science, Paper & Wood
WOS记录号WOS:000384922400016
引用统计
被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/14010
专题中国科学院广州能源研究所
作者单位1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Peoples R China
2.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
3.North Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA
4.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式
GB/T 7714
Li, Wenzhi,Xu, Zhiping,Zhang, Tingwei,et al. Catalytic Conversion of Biomass-derived Carbohydrates into 5-Hydroxymethylfurfural using a Strong Solid Acid Catalyst in Aqueous gamma-Valerolactone[J]. BIORESOURCES,2016,11(3):5839-5853.
APA Li, Wenzhi.,Xu, Zhiping.,Zhang, Tingwei.,Li, Guojun.,Jameel, Hasan.,...&Ma, Longlong.(2016).Catalytic Conversion of Biomass-derived Carbohydrates into 5-Hydroxymethylfurfural using a Strong Solid Acid Catalyst in Aqueous gamma-Valerolactone.BIORESOURCES,11(3),5839-5853.
MLA Li, Wenzhi,et al."Catalytic Conversion of Biomass-derived Carbohydrates into 5-Hydroxymethylfurfural using a Strong Solid Acid Catalyst in Aqueous gamma-Valerolactone".BIORESOURCES 11.3(2016):5839-5853.
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