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Facile synthesis of MoS2/B-TiO2 nanosheets with exposed {001} facets and enhanced visible-light-driven photocatalytic H-2 production activity
Yang, Xixian1; Huang, Hongyu1; Jin, Bei2; Luo, Jin2; Zhou, Xiaosong2,3
2016
发表期刊RSC ADVANCES
卷号6期号:108页码:107075-107080
摘要Cocatalysts have been extensively used to accelerate the rate of hydrogen evolution in semiconductor-based photocatalytic systems; however, the influence of interface states between the semiconductor and cocatalyst has rarely been investigated. Herein, we demonstrated a feasible strategy of heterogeneous structure to enhance visible light hydrogen generation of the MoS2/B-TiO2 system. Loading of MoS2 nanosheets on the surface of anatase boron doped TiO2 (B-TiO2) nanosheets with exposed {001} facets considerably increases the interfacial contact. At an optimal ratio of 1.0 wt% MoS2, the MoS2/B-TiO2 hybrid photocatalyst showed the highest H-2 evolution rate of 0.50 mmol h(-1) g(-1), which is almost 6 times higher than that of pure B-TiO2 nanosheets. More importantly, the MoS2/B-TiO2 hybrid photocatalyst exhibited photocatalytic activity much higher than that of Pt/B-TiO2 nanosheets and the simple mechanical mixing of B-TiO2 and MoS2 nanosheets photocatalysts. The decisive factor in improving the photocatalytic H-2 production activity is an intimate and large contact interface between the light-harvesting semiconductor and cocatalyst. The effective charge transfers from B-TiO2 to MoS2 was demonstrated by the significant enhancement of the photocurrent responses in MoS2/B-TiO2 hybrid electrodes. This study created new opportunities for designing and constructing highly efficient visible light photocatalysts by surface modification or doping.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
资助者Guangdong Natural Science Foundation(2015A030313893) ; Lingnan Normal University Natural Science Foundation(LZL1505) ; Zhanjiang Special Competitive Allocation of Financial Capital Project(2015A02028) ; Overseas Scholarship Program for Elite Young and Middle-aged Teachers of Lingnan Normal University ; Guangdong Natural Science Foundation(2015A030313893) ; Lingnan Normal University Natural Science Foundation(LZL1505) ; Zhanjiang Special Competitive Allocation of Financial Capital Project(2015A02028) ; Overseas Scholarship Program for Elite Young and Middle-aged Teachers of Lingnan Normal University
DOI10.1039/c6ra23838f
研究领域[WOS]Chemistry
关键词[WOS]TITANIUM-DIOXIDE NANOCRYSTALS ; EXFOLIATED METALLIC MOS2 ; ANATASE TIO2 NANOSHEETS ; HYDROGEN EVOLUTION ; PHOSPHIDE NANOPARTICLES ; GENERATING HYDROGEN ; PERFORMANCE ; WATER ; DEGRADATION ; IRRADIATION
收录类别SCI
语种英语
资助者Guangdong Natural Science Foundation(2015A030313893) ; Lingnan Normal University Natural Science Foundation(LZL1505) ; Zhanjiang Special Competitive Allocation of Financial Capital Project(2015A02028) ; Overseas Scholarship Program for Elite Young and Middle-aged Teachers of Lingnan Normal University ; Guangdong Natural Science Foundation(2015A030313893) ; Lingnan Normal University Natural Science Foundation(LZL1505) ; Zhanjiang Special Competitive Allocation of Financial Capital Project(2015A02028) ; Overseas Scholarship Program for Elite Young and Middle-aged Teachers of Lingnan Normal University
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000389330700118
引用统计
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/14007
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China
2.Lingnan Normal Univ, Inst Phys Chem, Sch Chem & Chem Engn, Zhanjiang 524048, Peoples R China
3.Griffith Univ, Environm Futures Res Inst, Griffith Sch Environm, Ctr Clean Environm & Energy, Gold Coast, Qld 4222, Australia
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GB/T 7714
Yang, Xixian,Huang, Hongyu,Jin, Bei,et al. Facile synthesis of MoS2/B-TiO2 nanosheets with exposed {001} facets and enhanced visible-light-driven photocatalytic H-2 production activity[J]. RSC ADVANCES,2016,6(108):107075-107080.
APA Yang, Xixian,Huang, Hongyu,Jin, Bei,Luo, Jin,&Zhou, Xiaosong.(2016).Facile synthesis of MoS2/B-TiO2 nanosheets with exposed {001} facets and enhanced visible-light-driven photocatalytic H-2 production activity.RSC ADVANCES,6(108),107075-107080.
MLA Yang, Xixian,et al."Facile synthesis of MoS2/B-TiO2 nanosheets with exposed {001} facets and enhanced visible-light-driven photocatalytic H-2 production activity".RSC ADVANCES 6.108(2016):107075-107080.
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