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An equation for determining methane densities in fluid inclusions with Raman shifts
Zhang, Jianli1,2; Qiao, Shaohua3; Lu, Wanjun4; Hu, Qingcheng1; Chen, Shuguang1,2; Liu, Yuan1
2016-12-01
发表期刊JOURNAL OF GEOCHEMICAL EXPLORATION
卷号171页码:20-28
摘要Raman shift of the C-H symmetric stretching band (v(1)) of methane can be used to calculate the pressure and density of methane in fluid inclusions. However, previous numerical functions for Raman band shifts and methane density are only suitable for methane with densities lower than 03 g/cm(3). In this study, Raman shifts for pure CH4 were systematically measured at 25 degrees C and pressures up to 150 MPa. Parameters of the long range attractive forces were fitted, and Raman shifts of CH4 were calculated with hard sphere model for density up to 0.55 g/cm(3). Based on experimental data and theoretical calculation, a unified equation was established to calculate the density of methane gas from Raman,shifts over a wide density ranges up to 0.55 g/cm(3):
文章类型Article
关键词Fluid Inclusion Methane Density Raman Shifts Unified Equation Pb-zn Deposit
WOS标题词Science & Technology ; Physical Sciences
DOI10.1016/j.gexplo.2015.12.003
研究领域[WOS]Geochemistry & Geophysics
关键词[WOS]VIBRATIONAL FREQUENCY-SHIFTS ; SPECTROSCOPIC CHARACTERIZATION ; QUANTITATIVE COMPOSITION ; PRESSURE DETERMINATION ; MOLECULAR COMPRESSION ; GAS-MIXTURES ; SYSTEM ; CH4 ; CALIBRATION ; DEPENDENCE
收录类别SCI ; ISTP
语种英语
WOS类目Geochemistry & Geophysics
WOS记录号WOS:000388780200003
引用统计
被引频次:37[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/14006
专题中国科学院广州能源研究所
作者单位1.China Univ Geosci, Fac Earth Resources, Minist Educ, Key Lab Tecton & Petr Resources, Wuhan 430074, Peoples R China
2.Huabei Oil Field Co, Explorat & Dev Res Inst, Renqiu 062552, Peoples R China
3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
4.China Univ Geosci, State Key Lab Geol Proc & Mineral Resources, Wuhan 430074, Peoples R China
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Zhang, Jianli,Qiao, Shaohua,Lu, Wanjun,et al. An equation for determining methane densities in fluid inclusions with Raman shifts[J]. JOURNAL OF GEOCHEMICAL EXPLORATION,2016,171:20-28.
APA Zhang, Jianli,Qiao, Shaohua,Lu, Wanjun,Hu, Qingcheng,Chen, Shuguang,&Liu, Yuan.(2016).An equation for determining methane densities in fluid inclusions with Raman shifts.JOURNAL OF GEOCHEMICAL EXPLORATION,171,20-28.
MLA Zhang, Jianli,et al."An equation for determining methane densities in fluid inclusions with Raman shifts".JOURNAL OF GEOCHEMICAL EXPLORATION 171(2016):20-28.
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