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Characterization of the decomposition behaviors of catalytic pyrolysis of wood using copper and potassium over thermogravimetric and Py-GC/MS analysis
Xing, Shiyou1,2,3; Yuan, Haoran1,2,4; Huhetaoli1,2,4; Qi, Yujie1,2; Lv, Pengmei1,2,4; Yuan, Zhenhong1,2,4; Chen, Yong1,2
2016-11-01
发表期刊ENERGY
卷号114页码:634-646
摘要Characterizing the pyrolysis of inorganic matter-rich biomass is important for the preparation of bio-fuel precursors. Here, thermogravimetric and pyrolysis gas chromatography/mass spectroscopy (Py-GC/MS) were employed to elucidate the specific pyrolysis mechanisms of demineralized wood dust (AWD) impregnated with varying amounts of the inorganic compounds, copper and potassium. During the pyrolysis process, there was a dramatic decomposition of hemicellulose (at 200-320 degrees C) and of cellulose (at 320-420 degrees C), along with slow lignin degradation. The decomposition of hemicellulose was substantially promoted with an increasing amount of copper. In addition, a decreased amount of aldehydes and phenols was observed, indicating a lower level of cellulose and lignin degradation, which led to more generation of bio-fuel precursors (C-5-C-16). In contrast to copper, potassium substantially promoted the decomposition of cellulose and lignin, but had negligible effect on hemicellulose. In the presence of both copper and potassium, the latter had a more dominant role causing an increased amount of small molecular compounds (C-2-C-4, i.e., from 10.91% to 22.12%), and decreased amounts of bio-fuel precursors (i.e., from 62.19% to 52.49%). The various decomposition pathways that might be involved in the catalytic pyrolysis of wood using copper and potassium are discussed. (C) 2016 Elsevier Ltd. All rights reserved.
文章类型Article
关键词Thermogravimetric Analysis Pyrolysis Gas Chromatography/mass Spectroscopy Wood Pyrolysis Copper Potassium Bio-fuel
WOS标题词Science & Technology ; Physical Sciences ; Technology
资助者National Natural Science Foundation of China(51406207) ; Youth Innovation Promotion Association CAS(2014320) ; scientific research and equipment development project by Chinese Academy of Sciences(YZ201516) ; Special Support Plan of Guangdong Province(2014TQ01Z379) ; National Natural Science Foundation of China(51406207) ; Youth Innovation Promotion Association CAS(2014320) ; scientific research and equipment development project by Chinese Academy of Sciences(YZ201516) ; Special Support Plan of Guangdong Province(2014TQ01Z379)
DOI10.1016/j.energy.2016.07.154
研究领域[WOS]Thermodynamics ; Energy & Fuels
关键词[WOS]FLUIDIZED-BED REACTOR ; BIO-OIL ; CARBON-DIOXIDE ; MAIN COMPONENTS ; TREATED WOOD ; HEATING RATE ; POPLAR WOOD ; CELLULOSE ; BIOMASS ; LIGNIN
收录类别SCI
语种英语
资助者National Natural Science Foundation of China(51406207) ; Youth Innovation Promotion Association CAS(2014320) ; scientific research and equipment development project by Chinese Academy of Sciences(YZ201516) ; Special Support Plan of Guangdong Province(2014TQ01Z379) ; National Natural Science Foundation of China(51406207) ; Youth Innovation Promotion Association CAS(2014320) ; scientific research and equipment development project by Chinese Academy of Sciences(YZ201516) ; Special Support Plan of Guangdong Province(2014TQ01Z379)
WOS类目Thermodynamics ; Energy & Fuels
WOS记录号WOS:000387194800050
引用统计
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/13971
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China
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Xing, Shiyou,Yuan, Haoran,Huhetaoli,et al. Characterization of the decomposition behaviors of catalytic pyrolysis of wood using copper and potassium over thermogravimetric and Py-GC/MS analysis[J]. ENERGY,2016,114:634-646.
APA Xing, Shiyou.,Yuan, Haoran.,Huhetaoli.,Qi, Yujie.,Lv, Pengmei.,...&Chen, Yong.(2016).Characterization of the decomposition behaviors of catalytic pyrolysis of wood using copper and potassium over thermogravimetric and Py-GC/MS analysis.ENERGY,114,634-646.
MLA Xing, Shiyou,et al."Characterization of the decomposition behaviors of catalytic pyrolysis of wood using copper and potassium over thermogravimetric and Py-GC/MS analysis".ENERGY 114(2016):634-646.
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