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Cation exchange resin catalysed biodiesel production from used cooking oil (UCO): Investigation of impurities effect
Fu, Junying1; Li, Zhibing1; Xing, Shiyou1,3; Wang, Zhiyuan1; Miao, Changlin1; Lv, Pengmei1,2; Yuan, Zhenhong1,2
2016-10-01
发表期刊FUEL
卷号181页码:1058-1065
摘要Converting used cooking oil (UCO) into biodiesel using solid acid catalysts shows good prospective for renewable and clean bio-fuel production. However, impurities (metal ion, water, etc.) contained in UCO will have effect on its biodiesel production as well as to affect the activity of solid acids. These effects were explored by selecting two UCOs and their model oils (same AV, without impurities) as feedstock, two typical kinds of cation exchange resins Amberlyst 15 and Amberlyst BD20 as solid acid catalysts. The result indicated that metal ion (Fe3+) not only showed deactivation effect on resin catalyst by cationic exchange but also exhibited catalytic activity as Lewis acid when it is in free form. The deactivation effect of water formed hydrated proton (-H3O+-SO3) on resin catalyst cannot be alleviated by increasing methanol concentration but can be reduced through increasing reaction temperature. The organic acids, highly active in catalysing esterification reaction, showed synergistic effect with cation exchange resin. Under the co-effect of organic acid (UCO-1, 0.19 mmol H+ g(-1); UCO-2, 0.12 mmol H+ g(-1)), metal ions (UCO-1, Fe: 0.6 ppm, etc.; UCO-2, Fe: 9.4 ppm, etc.) and other impurities, UCO-1/UCO-2 showed a FFA conversion of 1.2-14.1%/4.5-13.5%, compared with -4.35-9.36%/0.96-8.09% for their model oils at reaction condition of catalyst-free, 70-110 degrees C, 3 h, methanol-to-FFA molar ratio of 15:1. (C) 2016 Elsevier Ltd. All rights reserved.
文章类型Article
关键词Biodiesel Used Cooking Oil Impurities Cation Exchange Resin
WOS标题词Science & Technology ; Technology
资助者National Natural Science Foundation of China(21576260) ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; Natural Science Foundation of Guangdong Province(2015A030313720) ; National Science & Technology Support Program(2014BAD02B07) ; National Natural Science Foundation of China(21576260) ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; Natural Science Foundation of Guangdong Province(2015A030313720) ; National Science & Technology Support Program(2014BAD02B07)
DOI10.1016/j.fuel.2016.04.131
研究领域[WOS]Energy & Fuels ; Engineering
关键词[WOS]FREE FATTY-ACIDS ; SOLID ACID ; OLEIC-ACID ; INCORPORATED SBA-15 ; ESTERIFICATION ; EFFICIENT ; TRANSESTERIFICATION ; DEACTIVATION ; SILICA ; DIESEL
收录类别SCI
语种英语
资助者National Natural Science Foundation of China(21576260) ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; Natural Science Foundation of Guangdong Province(2015A030313720) ; National Science & Technology Support Program(2014BAD02B07) ; National Natural Science Foundation of China(21576260) ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; Natural Science Foundation of Guangdong Province(2015A030313720) ; National Science & Technology Support Program(2014BAD02B07)
WOS类目Energy & Fuels ; Engineering, Chemical
WOS记录号WOS:000377328700106
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/13952
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan Province, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100040, Peoples R China
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Fu, Junying,Li, Zhibing,Xing, Shiyou,et al. Cation exchange resin catalysed biodiesel production from used cooking oil (UCO): Investigation of impurities effect[J]. FUEL,2016,181:1058-1065.
APA Fu, Junying.,Li, Zhibing.,Xing, Shiyou.,Wang, Zhiyuan.,Miao, Changlin.,...&Yuan, Zhenhong.(2016).Cation exchange resin catalysed biodiesel production from used cooking oil (UCO): Investigation of impurities effect.FUEL,181,1058-1065.
MLA Fu, Junying,et al."Cation exchange resin catalysed biodiesel production from used cooking oil (UCO): Investigation of impurities effect".FUEL 181(2016):1058-1065.
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