Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Enhanced esterification of oleic acid and methanol by deep eutectic solvent assisted Amberlyst heterogeneous catalyst | |
Pan, Ying1,2; Alam, Md. Asraful1,4; Wang, Zhongming1,4; Wu, Jingcheng1,4; Zhang, Yi1,4; Yuan, Zhenhong1,3,4 | |
2016-11-01 | |
发表期刊 | BIORESOURCE TECHNOLOGY |
卷号 | 220页码:543-548 |
摘要 | In present study, esterification of oleic acid with methanol using deep eutectic solvent (DES) assisted Amberlyst heterogeneous catalyst was investigated to produce biodiesel. Results showed that esterification efficiency was enhanced by the DES. The combined effect of DES on Amberlyst BD20 (BD20) is better than Amberlyst 15 (A-15) due to different structure. The optimal reaction conditions were 12:1 M ratio of methanol to oleic acid, 20% (wt/wt) catalyst (BD20-DES (2:8) and A-15-DES (8:2)) at 85 degrees C for 100 min with agitating at 200 rpm. The mechanism involved in catalysis and their capacity to reuse were studied. We proposed, Choline chloride-glycerol (Chcl-gly) DES could enhance the Amberlyst function due to the hydrogen bond effect on both DES and water. BD20 has fewer pores than A-15, have desirable performance in decreasing the inhibition the water during esterification of high FFA content and provide better performance in reuse. (C) 2016 Elsevier Ltd. All rights reserved. |
文章类型 | Article |
关键词 | Amberlyst Heterogeneous Catalyst Deep Eutectic Solvent Oleic Acid Esterification Biodiesel |
WOS标题词 | Science & Technology ; Life Sciences & Biomedicine ; Technology |
DOI | 10.1016/j.biortech.2016.08.113 |
研究领域[WOS] | Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels |
关键词[WOS] | BIODIESEL PRODUCTION ; CHOLINE CHLORIDE ; OIL ; OPTIMIZATION ; KINETICS |
收录类别 | SCI |
语种 | 英语 |
项目资助者 | National Natural Science Foundation of China(51476177) ; National Natural Science Foundation for research team of Guangdong, China(2016A030312007) |
WOS类目 | Agricultural Engineering ; Biotechnology & Applied Microbiology ; Energy & Fuels |
WOS记录号 | WOS:000384712900068 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/13948 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China 3.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan Province, Peoples R China 4.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China |
第一作者单位 | 中国科学院广州能源研究所 |
推荐引用方式 GB/T 7714 | Pan, Ying,Alam, Md. Asraful,Wang, Zhongming,et al. Enhanced esterification of oleic acid and methanol by deep eutectic solvent assisted Amberlyst heterogeneous catalyst[J]. BIORESOURCE TECHNOLOGY,2016,220:543-548. |
APA | Pan, Ying,Alam, Md. Asraful,Wang, Zhongming,Wu, Jingcheng,Zhang, Yi,&Yuan, Zhenhong.(2016).Enhanced esterification of oleic acid and methanol by deep eutectic solvent assisted Amberlyst heterogeneous catalyst.BIORESOURCE TECHNOLOGY,220,543-548. |
MLA | Pan, Ying,et al."Enhanced esterification of oleic acid and methanol by deep eutectic solvent assisted Amberlyst heterogeneous catalyst".BIORESOURCE TECHNOLOGY 220(2016):543-548. |
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