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Synthesis and electrochemical performance of cubic Co-doped Li4Ti5O12 anode material for high-performance lithium-ion batteries
Zhang, Congcong1; Shao, Dan2; Yu, Jingfang3; Zhang, Linzhi4; Huang, Xueyan1; Xu, Donghui1; Yu, Xiaoyuan1
2016-09-01
发表期刊JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷号776页码:188-192
摘要Co-doped Li4Ti5O12 (LCTO) anode material for lithium-ion battery was synthesized via a mechanic ball-milling activation and high temperature solid state reaction using CoCO3, TiO2 and Li2CO3 as raw material. The structure, morphology and electrochemical properties of LCTO sample are characterized by X-ray diffraction (XRD), scanning electronic morphology (SEM), galvanostatic charge-discharge tests, cyclic voltammetry (CV) and electron chemical impedance spectroscopy (EIS) measurements. The LCTO is well crystallized as a spinet structure without any detectable impurity phase with the doping of Co. Thus, LCTO exhibits improving cycling stability and rate capability as anode material for lithium ion batteries, which delivered the initial specific capacity of 250, 222, 188, 180, 149 and 118 mAh g(-1), at 0.1, 0.2,1.0, 2.0, 5.0 and 10.0 degrees C rate in the voltage range of 0.5-3.0 V respectively, and discharge capacity of 200 mAh g(-1) after 100 cycles at 0.1 degrees C. EIS results further show that the main reason for the improved electrochemical performance of LCTO is its reduced electrochemical impedance, which mainly due to the Co-doped modification leads to O vacancies then results in increase amount of embedded lithium in LCTO materials. (C) 2016 Elsevier B.V. All rights reserved.
文章类型Article
关键词Li-ion Battery High Temperature Solid Ball-milling Method Co-doping Li4ti5o12
WOS标题词Science & Technology ; Physical Sciences
资助者Guangdong Science and Technology Planning Project(2015A020209147) ; Guangdong Natural Science Foundation(9151064201000039) ; National Natural Science Foundation of China(51003034) ; Key Academic Program of the 3rd phase '211 Project'(2009B010100001) ; Guangdong Science and Technology Planning Project(2015A020209147) ; Guangdong Natural Science Foundation(9151064201000039) ; National Natural Science Foundation of China(51003034) ; Key Academic Program of the 3rd phase '211 Project'(2009B010100001)
DOI10.1016/j.jelechem.2016.07.017
研究领域[WOS]Chemistry ; Electrochemistry
关键词[WOS]HIGH-RATE CAPABILITY ; SOL-GEL METHOD ; RECHARGEABLE BATTERIES ; CARBON ; SPINEL ; TITANATE ; NANOPARTICLES ; MICROSPHERES ; NANOSHEETS ; STABILITY
收录类别SCI
语种英语
资助者Guangdong Science and Technology Planning Project(2015A020209147) ; Guangdong Natural Science Foundation(9151064201000039) ; National Natural Science Foundation of China(51003034) ; Key Academic Program of the 3rd phase '211 Project'(2009B010100001) ; Guangdong Science and Technology Planning Project(2015A020209147) ; Guangdong Natural Science Foundation(9151064201000039) ; National Natural Science Foundation of China(51003034) ; Key Academic Program of the 3rd phase '211 Project'(2009B010100001)
WOS类目Chemistry, Analytical ; Electrochemistry
WOS记录号WOS:000382348100026
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/11905
专题中国科学院广州能源研究所
作者单位1.South China Agr Univ, Coll Mat & Energy, Inst Biomat, Guangzhou 510642, Guangdong, Peoples R China
2.Guangzhou Inst Energy Testing, Guangzhou 510170, Guangdong, Peoples R China
3.Univ Connecticut, Inst Mat Sci, Storrs, CT 06269 USA
4.Chinese Acad Sci, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
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Zhang, Congcong,Shao, Dan,Yu, Jingfang,et al. Synthesis and electrochemical performance of cubic Co-doped Li4Ti5O12 anode material for high-performance lithium-ion batteries[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY,2016,776:188-192.
APA Zhang, Congcong.,Shao, Dan.,Yu, Jingfang.,Zhang, Linzhi.,Huang, Xueyan.,...&Yu, Xiaoyuan.(2016).Synthesis and electrochemical performance of cubic Co-doped Li4Ti5O12 anode material for high-performance lithium-ion batteries.JOURNAL OF ELECTROANALYTICAL CHEMISTRY,776,188-192.
MLA Zhang, Congcong,et al."Synthesis and electrochemical performance of cubic Co-doped Li4Ti5O12 anode material for high-performance lithium-ion batteries".JOURNAL OF ELECTROANALYTICAL CHEMISTRY 776(2016):188-192.
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