Carbon Nanotube-Based Solid Sulfonic Acids as Catalysts for Production of Fatty Acid Methyl Ester via Transesterification and Esterification

doi:10.1021/acssuschemeng.6b00156

GIEC OpenIR > 中国科学院广州能源研究所

	Carbon Nanotube-Based Solid Sulfonic Acids as Catalysts for Production of Fatty Acid Methyl Ester via Transesterification and Esterification
	Liu, Hang 1,2,3; Chen, Jinzhu2,3 ; Chen, Limin 4; Xu, Yisheng 1; Guo, Xuhong 1; Fang, Dingye 1
	2016-06-01
发表期刊	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷号	4 期号:6 页码:3140-3150
摘要	A series of polymer-carbon nanotube composite materials (CNT-P-SO3H) were prepared by covalent grafting of multiwalled carbon nanotubes (CNTs) with sulfonic acid-functionalized polymers (P-SO3H) including poly(3-vinyl-1-sulfonic acid imidazolium chloride)-grafted multiwalled CNTs (CNT-PVSAIC), poly(4-vinyl-1-sulfonic acid pyridinium chloride) -grafted multiwalled CNTs (CNT-PVSAPC), and poly(4-styrenesulfonic acid) -grafted multiwalled CNTs (CNT-PSSA). Such a functionalization method provides a facile route to obtain various polyelectrolyte brushes on the surfaces of CNTs in order to improve the dispersibility and modulate the acidity of CNTs to selectively introduce functional groups and densely create active sites over CNTs for potential catalytic applications. Both CNT-PVSAIC and CNT-PVSAPC consist of cationic polyelectrolyte chains functionalized by sulfonic acid groups, whereas CNT-PSSA is composed of anionic polymer brushes grafted by sulfonic acid groups. The physicochemical properties of CNT-P-SO3H were analyzed by BET, TGA, XRD, FT-IR, XPS, Raman, and HRTEM techniques. The resulting CNT-P-SO3H materials exhibit excellent catalytic activity as CNT-based solid acids in liquid phase transesterification of triglycerides with methanol and esterification of oleic acid with methanol, which are typical model reactions for biodiesel production. The outstanding catalytic performance of the CNT-P-SO3H catalysts is attributed to the combination of the mesoporous structure together with a well extended P-SO3H coating over the outer surface of the CNTs, providing the formation of a dense but uniform surface distribution of active sites.
文章类型	Article
关键词	Biodiesel Carbon Nanotubes Esterification Solid Acid Transesterification
WOS标题词	Science & Technology ; Physical Sciences ; Technology
DOI	10.1021/acssuschemeng.6b00156
研究领域[WOS]	Chemistry ; Engineering
关键词[WOS]	FUNCTIONALIZED PYRIDINIUM CHLORIDE ; METAL-ORGANIC FRAMEWORKS ; BIODIESEL PRODUCTION ; HETEROGENEOUS CATALYSTS ; PHOTOELECTRON-SPECTROSCOPY ; CHEMICAL CONVERSION ; EFFICIENT CATALYST ; OPTICAL-PROPERTIES ; VEGETABLE-OILS ; GRAPHENE OXIDE
收录类别	SCI
语种	英语
WOS类目	Chemistry, Multidisciplinary ; Engineering, Chemical
WOS记录号	WOS:000377425900026
引用统计	被引频次：75[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/11667
专题	中国科学院广州能源研究所
作者单位	1.E China Univ Sci & Technol, State Key Lab Chem Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China 4.S China Univ Technol, Coll Environm & Energy, Guangzhou Higher Educ Mega Ctr, 382 Zhonghuan Rd East, Guangzhou 510006, Guangdong, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Liu, Hang,Chen, Jinzhu,Chen, Limin,et al. Carbon Nanotube-Based Solid Sulfonic Acids as Catalysts for Production of Fatty Acid Methyl Ester via Transesterification and Esterification[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2016,4(6):3140-3150.
APA	Liu, Hang,Chen, Jinzhu,Chen, Limin,Xu, Yisheng,Guo, Xuhong,&Fang, Dingye.(2016).Carbon Nanotube-Based Solid Sulfonic Acids as Catalysts for Production of Fatty Acid Methyl Ester via Transesterification and Esterification.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,4(6),3140-3150.
MLA	Liu, Hang,et al."Carbon Nanotube-Based Solid Sulfonic Acids as Catalysts for Production of Fatty Acid Methyl Ester via Transesterification and Esterification".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 4.6(2016):3140-3150.