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Promising photovoltaic application of multi-walled carbon nanotubes in perovskites solar cells for retarding recombination
Wang, Junxia1; Li, Jingling1; Xu, Xueqing1; Bi, Zhuoneng1; Xu, Gang1; Shen, Honglie2
2016
发表期刊RSC ADVANCES
卷号6期号:48页码:42413-42420
摘要A facile spray deposition method was developed to prepare a high-quality perovskite layer under ambient conditions. However, the performance is expected to be further improved with substrate and the hole transport layer (HTL) optimization and device structure, for instance. MWCNTs with incorporated spiro-OMeTAD exhibited J(sc) of 22.13 mA cm(-2) and PCE of 10.42%. To infer the origin of the increasing J(sc) and PCE, the optical absorption performance, charge transfer and recombination performance were investigated tau, R-ct, R-rec as a function of voltage and EIS measurements revealed the lower transfer resistance and recombination rate in PSCs with MWCNTs compared with the PSCs without MWCNTs. The increased resistance in dark conditions and the dark J-V curves explain the slight changes in the V-oc. The SEM images showed that there were no MWCNTs aggregated on the surface of the spiro/MWCNTs composite layer and part of MWCNTs was uncovered by spiro-OMeTAD at the interface of HTM and Au electrode. The decreased I-D/I-G ratio from 0.90 to 0.68 demonstrated the increased interaction between MWCNTs and spiro-OMeTAD.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1039/c6ra04743b
研究领域[WOS]Chemistry
关键词[WOS]THIN-FILM ; NANOCOMPOSITES ; PERFORMANCE ; COMPOSITES ; ELECTRODE ; LAYERS
收录类别SCI
语种英语
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000375445500081
引用统计
被引频次:25[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/11278
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China
2.Changzhou Univ, Jiangsu Collaborat Innovat Ctr Photovolta Sci & E, Changzhou 213164, Jiangsu, Peoples R China
第一作者单位中国科学院广州能源研究所
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Wang, Junxia,Li, Jingling,Xu, Xueqing,et al. Promising photovoltaic application of multi-walled carbon nanotubes in perovskites solar cells for retarding recombination[J]. RSC ADVANCES,2016,6(48):42413-42420.
APA Wang, Junxia,Li, Jingling,Xu, Xueqing,Bi, Zhuoneng,Xu, Gang,&Shen, Honglie.(2016).Promising photovoltaic application of multi-walled carbon nanotubes in perovskites solar cells for retarding recombination.RSC ADVANCES,6(48),42413-42420.
MLA Wang, Junxia,et al."Promising photovoltaic application of multi-walled carbon nanotubes in perovskites solar cells for retarding recombination".RSC ADVANCES 6.48(2016):42413-42420.
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