Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Hydrogen production from bio-oil model compounds dry (CO2) reforming over Ni/Al2O3 catalyst | |
Fu, Ming1; Qi, Wei2; Xu, Qingli1; Zhang, Suping1; Yan, Yongjie1 | |
2016-01-21 | |
发表期刊 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY |
卷号 | 41期号:3页码:1494-1501 |
摘要 | Bio-oil model compounds dry (CO2) reforming for hydrogen production over Ni/Al2O3 catalyst is presented in this paper. The research investigates the effects of reaction conditions such as temperature, weight hourly space velocity of the aqueous phase (WHSV), CO2 to carbon in bio-oil ratio (CO2/Bio-oil) on hydrogen yield and products distribution. And also study the coke formation rates versus different reaction temperature and different CO2/Bio-oil ratio. Meanwhile analyze the types of carbon deposited on Ni/Al2O3 catalyst. The experimental results show that, the optimum reaction temperature is 700 degrees C, CO2/Bio-oil is 0.75, WHSV is 0.9 h(-1), under these conditions, hydrogen yield and bio-oil model compounds conversion reach 88.19% and 96.87% respectively, the molar ratio of H-2/CO reaches 1.08. The coke formation rate exists a maximum at 600 degrees C, higher temperature (>600 degrees C) and higher CO2/Bio-oil (>0.75) are all good for carbon elimination of dry reforming. The forms of carbon deposit on Ni/Al2O3 catalyst are mainly filamentous carbon and graphitic carbon. Copyright (c) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. |
文章类型 | Article |
关键词 | Dry Reforming Bio-oil Hydrogen Carbon Deposition |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
DOI | 10.1016/j.ijhydene.2015.11.104 |
研究领域[WOS] | Chemistry ; Electrochemistry ; Energy & Fuels |
关键词[WOS] | BIOMASS STEAM GASIFICATION ; NOBLE-METAL CATALYSTS ; SUPERCRITICAL WATER ; SYNGAS PRODUCTION ; GAS-PRODUCTION ; BED REACTOR ; ACETIC-ACID ; RICH GAS ; COAL ; CH4 |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Chemistry, Physical ; Electrochemistry ; Energy & Fuels |
WOS记录号 | WOS:000369461500013 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/11012 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.E China Univ Sci & Technol, Minist Educ, Key Lab Coal Gasificat & Energy Chem Engn, Res Ctr Biomass Energy, Shanghai 200237, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou, Guangdong, Peoples R China |
推荐引用方式 GB/T 7714 | Fu, Ming,Qi, Wei,Xu, Qingli,et al. Hydrogen production from bio-oil model compounds dry (CO2) reforming over Ni/Al2O3 catalyst[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2016,41(3):1494-1501. |
APA | Fu, Ming,Qi, Wei,Xu, Qingli,Zhang, Suping,&Yan, Yongjie.(2016).Hydrogen production from bio-oil model compounds dry (CO2) reforming over Ni/Al2O3 catalyst.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,41(3),1494-1501. |
MLA | Fu, Ming,et al."Hydrogen production from bio-oil model compounds dry (CO2) reforming over Ni/Al2O3 catalyst".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 41.3(2016):1494-1501. |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论