Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Effect of Particle Microstructure on Sulfuric Acid Distribution During Biomass Hydrolysis | |
Qi, W.; Zhuang, X.; Zhang, Y.; Wang, Q.; Yu, Q.; Yuan, Z. | |
2015 | |
发表期刊 | ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS |
卷号 | 37期号:23页码:2524-2534 |
摘要 | When sulfuric acid is used to hydrolyze biomass, besides the macro factors (reaction temperature, acid concentration, reaction time, and ratio of solid to liquid), the diffusion rate of the acid into the biomass particle is also an important factor that affects the hydrolysis. In this article, pine wood sawdust was taken as test material (temperature: 433.15-463.15 K; sulfuric acid concentration: 10 Kg/m(3); ratio of L/S: 9; reaction time: 0-1,800 sec) and a distribution model of sulfuric acid was established by studying the diffusion characteristics in the heterogeneous phase consisting of sawdust and acid solution. Comparison between the calculated results from the model and experimental ones proved that the established model could satisfactorily predict the diffusion process of sulfuric acid into the sawdust particle during the reaction. Based on the distribution model, the effects of particle microstructure on the sulfuric acid concentration distribution were investigated. It indicates that particle size and porosity are the important factors that affect sulfuric acid diffusion in hydrolysis and the effect of porosity includes that from tortuosity. This study has a numerical description of sulfuric acid distribution in the bulk flow and within the particle during the reaction, and is of great significance in the further study of biomass hydrolysis mechanism. |
文章类型 | Article |
关键词 | Acid Hydrolysis Biomass Diffusion Model Microstructure Sulfuric Acid |
WOS标题词 | Science & Technology ; Technology ; Life Sciences & Biomedicine |
DOI | 10.1080/15567036.2012.688089 |
研究领域[WOS] | Energy & Fuels ; Engineering ; Environmental Sciences & Ecology |
关键词[WOS] | DIFFUSION ; PRETREATMENT ; WOOD |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Energy & Fuels ; Engineering, Chemical ; Environmental Sciences |
WOS记录号 | WOS:000366277000004 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10924 |
专题 | 中国科学院广州能源研究所 |
作者单位 | Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China |
推荐引用方式 GB/T 7714 | Qi, W.,Zhuang, X.,Zhang, Y.,et al. Effect of Particle Microstructure on Sulfuric Acid Distribution During Biomass Hydrolysis[J]. ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS,2015,37(23):2524-2534. |
APA | Qi, W.,Zhuang, X.,Zhang, Y.,Wang, Q.,Yu, Q.,&Yuan, Z..(2015).Effect of Particle Microstructure on Sulfuric Acid Distribution During Biomass Hydrolysis.ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS,37(23),2524-2534. |
MLA | Qi, W.,et al."Effect of Particle Microstructure on Sulfuric Acid Distribution During Biomass Hydrolysis".ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS 37.23(2015):2524-2534. |
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