Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Hydrogenation and hydrodeoxygenation of difurfurylidene acetone to liquid alkanes over Raney Ni and the supported Pt catalysts | |
Li, Yuping; Huang, Xiaoming; Zhang, Qian; Chen, Lungang; Zhang, Xinghua; Wang, Tiejun; Ma, Longlong | |
2015-12-15 | |
发表期刊 | APPLIED ENERGY |
卷号 | 160 |
摘要 | Direct HDO process for difurfurylidene acetone dimer (F2A) conversion to liquid alkanes (C8 C14) at 260 degrees C in a batch reactor was investigated over different material supported 1 wt%Pt catalysts, including SAPO-11, HZSM-5, SiO2-Al2O3, MCM-22, and home-made SiO2-ZrO2. CS-Cm alkanes of 55.8% was obtained over the optimized I wt%Pt/SiO2-ZrO2 due to its proper pore size of 9.0 nm and moderate acidic centers, together with more than 10% carbon yield of the oxygenated hydrocarbons, including C11-C13 chain alcohols 82 ketones and the hydrogenated F(2)A dimers with furan ring (H-F(2)A dimers). To improve the liquid alkane yield, a two-step process for F(2)A conversion was also investigated, which included low-temperature hydrogenation at 50 C over Raney Ni catalyst in a batch reactor and the subsequent high-temperature hydrodeoxygenation (HDO) at 280 degrees C over 1 wt%Pt/SiO2 ZrO2 in a fixed-bed reactor. The selectivity of 1,5-di(tetrahydro-2-furany1)-3-pentanol (II-c) was the highest of 83.0% among the hydrogenated intermediates of H-F2A dimers due to the protonation effect of methanol as the solvent and the hydrogenation of C=C bonds by Ni active centers. In the same time, the high content of this saturated alcohol H-dimer of II-C increased the solubility and stability of the intermediates in methanol solvent. High carbon yield of C-8-C-14 alkanes of 82.9%(mol) was obtained after oxygen atom removal from H-F(2)A dimers via, the second-step HDO reaction. Long time operation showed the stability of 1 wt%Pt/SiO2-ZrO2 as HDO catalyst, deduced from the steady phase structure, acidity of SiO2 ZrO2 support and Pt active centers by catalyst characterization. (C) 2015 Elsevier Ltd. All rights reserved. |
文章类型 | Article |
关键词 | Hydrogenation/hydrodeoxygenation Difurfurylidene Acetone Liquid Alkanes Raney Ni Pt Catalysts Catalytic Conversion |
WOS标题词 | Science & Technology ; Technology |
DOI | 10.1016/j.apenergy.2015.02.077 |
研究领域[WOS] | Energy & Fuels ; Engineering |
关键词[WOS] | FUEL RANGE ALKANES ; AQUEOUS-PHASE ; ALDOL-CONDENSATION ; BIOMASS ; CHEMICALS ; LIGNIN ; HYDROCARBONS ; CONVERSION ; OXIDE ; JET |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Energy & Fuels ; Engineering, Chemical |
WOS记录号 | WOS:000364890700098 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10902 |
专题 | 中国科学院广州能源研究所 |
作者单位 | Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
第一作者单位 | 中国科学院广州能源研究所 |
推荐引用方式 GB/T 7714 | Li, Yuping,Huang, Xiaoming,Zhang, Qian,et al. Hydrogenation and hydrodeoxygenation of difurfurylidene acetone to liquid alkanes over Raney Ni and the supported Pt catalysts[J]. APPLIED ENERGY,2015,160. |
APA | Li, Yuping.,Huang, Xiaoming.,Zhang, Qian.,Chen, Lungang.,Zhang, Xinghua.,...&Ma, Longlong.(2015).Hydrogenation and hydrodeoxygenation of difurfurylidene acetone to liquid alkanes over Raney Ni and the supported Pt catalysts.APPLIED ENERGY,160. |
MLA | Li, Yuping,et al."Hydrogenation and hydrodeoxygenation of difurfurylidene acetone to liquid alkanes over Raney Ni and the supported Pt catalysts".APPLIED ENERGY 160(2015). |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论