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Production of 5-Hydroxymethylfurfural and Furfural from Lignocellulosic Biomass in Water-Tetrahydrofuran Media with Sodium Bisulfate
Shi, Ning1,2; Liu, Qi-ying1; Wang, Tie-jun1; Zhang, Qi1; Ma, Long-long1; Cai, Chi-liu1
2015-10-01
Source PublicationCHINESE JOURNAL OF CHEMICAL PHYSICS
Volume28Issue:5
Abstract5-Hydroxymethylfurfural (HMF) and furfural (FF), two bio-based platform chemicals, were produced from various raw lignocellulosic materials (corncob, corn stover, wheat straw, rice straw and sugarcane bagasse) in a water-tetrahydrofuran media by using NaHSO4 as catalyst. The influences of reaction temperature (160-200 degrees C), reaction time (30-120 min), solvent volume ratio, feedstock concentration (2.4wt%-11.1wt%) and catalyst dosage were studied. The highest HMF and FF yields obtained from corncob were 47mol% and 56mol% under condition of 190 degrees C, 90 min, 10/1 of THF/H2O. Besides, the lignin in the raw biomass was also depolymerized into organosolv lignin.
SubtypeArticle
Keyword5-hydroxymethylfurfural Furfural Lignocellulosic Biomass Hydrolysis Dehydration Tetrahydrofuran Sodium Bisulfate
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1063/1674-0068/28/cjcp1501008
WOS Subject ExtendedPhysics
WOS KeywordSTRUCTURAL-CHARACTERIZATION ; CATALYTIC CONVERSION ; IONIC LIQUIDS ; CHEMICALS ; CELLULOSE ; ACID ; ORGANOSOLV ; LIGNIN ; PRETREATMENT ; SUGARS
Indexed BySCI
Language英语
WOS SubjectPhysics, Atomic, Molecular & Chemical
WOS IDWOS:000364503400018
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10891
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, CAS Key Lab Renewable Energy, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.Guizhou Inst Technol, Sch Chem Engn, Guiyang 550003, Peoples R China
Recommended Citation
GB/T 7714
Shi, Ning,Liu, Qi-ying,Wang, Tie-jun,et al. Production of 5-Hydroxymethylfurfural and Furfural from Lignocellulosic Biomass in Water-Tetrahydrofuran Media with Sodium Bisulfate[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2015,28(5).
APA Shi, Ning,Liu, Qi-ying,Wang, Tie-jun,Zhang, Qi,Ma, Long-long,&Cai, Chi-liu.(2015).Production of 5-Hydroxymethylfurfural and Furfural from Lignocellulosic Biomass in Water-Tetrahydrofuran Media with Sodium Bisulfate.CHINESE JOURNAL OF CHEMICAL PHYSICS,28(5).
MLA Shi, Ning,et al."Production of 5-Hydroxymethylfurfural and Furfural from Lignocellulosic Biomass in Water-Tetrahydrofuran Media with Sodium Bisulfate".CHINESE JOURNAL OF CHEMICAL PHYSICS 28.5(2015).
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