Conversion of corn stalk into furfural using a novel heterogeneous strong acid catalyst in gamma-valerolactone

doi:10.1016/j.biortech.2015.09.104

GIEC OpenIR > 中国科学院广州能源研究所

	Conversion of corn stalk into furfural using a novel heterogeneous strong acid catalyst in gamma-valerolactone
	Xu, Zhiping 1; Li, Wenzhi 2; Du, Zhijie 2; Wu, Hao 2; Jameel, Hasan 3; Chang, Hou-min 3; Ma, Longlong 4
	2015-12-01
发表期刊	BIORESOURCE TECHNOLOGY
卷号	198 页码:764-771
摘要	A novel solid acid catalyst was prepared by the copolymerization of p-toluenesulfonic acid and paraformaldehyde and then characterized by FT-IR, TG/DTG, HRTEM and N-2-BET. Furfural was successfully produced by the dehydration of xylose and xylan using the novel catalyst in gamma-valerolactone. This investigation focused on effects of various reaction conditions including solvent, acid catalyst, reaction temperature, residence time, water concentration, xylose loading and catalyst dosage on the dehydration of xylose to furfural. It was found that the solid catalyst displayed extremely high activity for furfural production. 80.4% furfural yield with 98.8% xylose conversion was achieved at 170 degrees C for 10 min. The catalyst could be recycled at least five times without significant loss of activity. Furthermore, 83.5% furfural yield and 19.5% HMF yield were obtained from raw corn stalk under more severe conditions (190 degrees C for 100 min). (C) 2015 Elsevier Ltd. All rights reserved.
文章类型	Article
关键词	Furfural Xylose Corn Stalk Ptsa-pom Catalyst Gamma-valerolactone
WOS标题词	Science & Technology ; Life Sciences & Biomedicine ; Technology
DOI	10.1016/j.biortech.2015.09.104
研究领域[WOS]	Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels
关键词[WOS]	D-XYLOSE ; IONIC LIQUID ; LIGNOCELLULOSIC BIOMASS ; SELECTIVE CONVERSION ; SUGAR PRODUCTION ; LEVULINIC ACID ; MALEIC-ACID ; SOLID ACIDS ; HEMICELLULOSE ; XYLAN
收录类别	SCI
语种	英语
WOS类目	Agricultural Engineering ; Biotechnology & Applied Microbiology ; Energy & Fuels
WOS记录号	WOS:000363487500097
引用统计	被引频次：90[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10883
专题	中国科学院广州能源研究所
作者单位	1.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China 2.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Peoples R China 3.N Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Xu, Zhiping,Li, Wenzhi,Du, Zhijie,et al. Conversion of corn stalk into furfural using a novel heterogeneous strong acid catalyst in gamma-valerolactone[J]. BIORESOURCE TECHNOLOGY,2015,198:764-771.
APA	Xu, Zhiping.,Li, Wenzhi.,Du, Zhijie.,Wu, Hao.,Jameel, Hasan.,...&Ma, Longlong.(2015).Conversion of corn stalk into furfural using a novel heterogeneous strong acid catalyst in gamma-valerolactone.BIORESOURCE TECHNOLOGY,198,764-771.
MLA	Xu, Zhiping,et al."Conversion of corn stalk into furfural using a novel heterogeneous strong acid catalyst in gamma-valerolactone".BIORESOURCE TECHNOLOGY 198(2015):764-771.