Formation Kinetics of Cyclopentane plus Methane Hydrates in Brine Water Systems and Raman Spectroscopic Analysis

doi:10.1021/acs.energyfuels.5b01416

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	Formation Kinetics of Cyclopentane plus Methane Hydrates in Brine Water Systems and Raman Spectroscopic Analysis
	Lv, Qiunan1,2 ; Li, Lu 1,2,3; Li, Xiaosen1,2 ; Chen, Zhaoyang 1,2
	2015-09-01
发表期刊	ENERGY & FUELS
卷号	29 期号:9 页码:6104-6110
摘要	The kinetics of the formation of cyclopentane (CP) + methane (CH4) hydrates are studied to find the optimum condition for the rapid hydrate formation under the submarine condition (NaCl mass fraction of 0.035, around 277.15 K and 12 MPa). The influences of the CP/liquid phase volume ratio and the volume of the liquid phase on the amount of gas uptake and CH4 consumption rate are determined. The results show that the high volume ratio of CP/liquid phase is favorable for the rapid formation of CP + CH4 hydrates. There is an optimal ratio of the liquid phase volume for obtaining the highest gas consumption. Raman spectrum analyses for CP + CH4 hydrates are carried out to examine the hydrate structure and guest molecule occupation. The results show that CP mainly occupies the large cavities (5(12)6(4)) and CH4 is encapsulated in the small cavities (5(12)) of the structure II hydrates. When the volume ratio of the CP/liquid phase is 0.05, CP with CH4 also occupies the large cavities (5(12)6(4)).
文章类型	Article
WOS标题词	Science & Technology ; Technology
DOI	10.1021/acs.energyfuels.5b01416
研究领域[WOS]	Energy & Fuels ; Engineering
关键词[WOS]	BINARY CLATHRATE HYDRATE ; CARBON-DIOXIDE CAPTURE ; PRODUCTION BEHAVIOR ; PHASE-EQUILIBRIUM ; GUEST MOLECULES ; GAS-PRODUCTION ; NATURAL-GAS ; STIMULATION ; MIXTURE ; CRYSTALLIZATION
收录类别	SCI
语种	英语
WOS类目	Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:000363068200061
引用统计	被引频次：27[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10879
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Guangzhou Ctr Gas Hydrate Res, Guangzhou 510640, Guangdong, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100083, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Lv, Qiunan,Li, Lu,Li, Xiaosen,et al. Formation Kinetics of Cyclopentane plus Methane Hydrates in Brine Water Systems and Raman Spectroscopic Analysis[J]. ENERGY & FUELS,2015,29(9):6104-6110.
APA	Lv, Qiunan,Li, Lu,Li, Xiaosen,&Chen, Zhaoyang.(2015).Formation Kinetics of Cyclopentane plus Methane Hydrates in Brine Water Systems and Raman Spectroscopic Analysis.ENERGY & FUELS,29(9),6104-6110.
MLA	Lv, Qiunan,et al."Formation Kinetics of Cyclopentane plus Methane Hydrates in Brine Water Systems and Raman Spectroscopic Analysis".ENERGY & FUELS 29.9(2015):6104-6110.