High yield of renewable hexanes by direct hydrolysis-hydrodeoxygenation of cellulose in an aqueous phase catalytic system

doi:10.1039/c4ra14304c

GIEC OpenIR > 中国科学院广州能源研究所

	High yield of renewable hexanes by direct hydrolysis-hydrodeoxygenation of cellulose in an aqueous phase catalytic system
	Liu, Yong 1,2; Chen, Lungang 1; Wang, Tiejun1 ; Zhang, Xinghua1 ; Long, Jinxing 1; Zhang, Qi1 ; Ma, Longlong1
	2015
发表期刊	RSC ADVANCES
卷号	5 期号:15 页码:11649-11657
摘要	In aqueous phosphoric acid, cellulose was efficiently converted into hexanes using a Ru/C catalyst combined with layered compounds or silica-alumina materials. In this process, the direct production of hexanes from cellulose can be improved by suppressing the formation of isosorbide, which makes it difficult to yield hexanes by further hydrodeoxygenation. As the co-catalyst, layered compounds showed a significant inhibition effect on the formation of isosorbide from sorbitol due to the steric restrictions of sorbitol dehydration within the interlayers of layered compounds. Typically, layered LiNbMoO6 played a great role in promoting the production of hexanes directly from cellulose and a promising yield (72% carbon mol) of hexanes was obtained. In addition, the protonic acid, H3PO4, offered efficient catalysis for the hydrolysis of cellulose and the dehydration of the sorbitol hydroxyl moiety.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1039/c4ra14304c
研究领域[WOS]	Chemistry
关键词[WOS]	TRANSITION-METAL OXIDE ; SOLID ACID CATALYSTS ; ONE-POT CONVERSION ; NI/HZSM-5 CATALYSTS ; ETHYLENE-GLYCOL ; GLYCOLALDEHYDE PHOSPHATE ; LIQUID ALKANES ; C-6 ALDITOLS ; RANEY NI ; BIOMASS
收录类别	SCI
语种	英语
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000348986900095
引用统计	被引频次：34[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10805
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Liu, Yong,Chen, Lungang,Wang, Tiejun,et al. High yield of renewable hexanes by direct hydrolysis-hydrodeoxygenation of cellulose in an aqueous phase catalytic system[J]. RSC ADVANCES,2015,5(15):11649-11657.
APA	Liu, Yong.,Chen, Lungang.,Wang, Tiejun.,Zhang, Xinghua.,Long, Jinxing.,...&Ma, Longlong.(2015).High yield of renewable hexanes by direct hydrolysis-hydrodeoxygenation of cellulose in an aqueous phase catalytic system.RSC ADVANCES,5(15),11649-11657.
MLA	Liu, Yong,et al."High yield of renewable hexanes by direct hydrolysis-hydrodeoxygenation of cellulose in an aqueous phase catalytic system".RSC ADVANCES 5.15(2015):11649-11657.