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High yield of renewable hexanes by direct hydrolysis-hydrodeoxygenation of cellulose in an aqueous phase catalytic system
Liu, Yong1,2; Chen, Lungang1; Wang, Tiejun1; Zhang, Xinghua1; Long, Jinxing1; Zhang, Qi1; Ma, Longlong1
2015
发表期刊RSC ADVANCES
卷号5期号:15页码:11649-11657
摘要In aqueous phosphoric acid, cellulose was efficiently converted into hexanes using a Ru/C catalyst combined with layered compounds or silica-alumina materials. In this process, the direct production of hexanes from cellulose can be improved by suppressing the formation of isosorbide, which makes it difficult to yield hexanes by further hydrodeoxygenation. As the co-catalyst, layered compounds showed a significant inhibition effect on the formation of isosorbide from sorbitol due to the steric restrictions of sorbitol dehydration within the interlayers of layered compounds. Typically, layered LiNbMoO6 played a great role in promoting the production of hexanes directly from cellulose and a promising yield (72% carbon mol) of hexanes was obtained. In addition, the protonic acid, H3PO4, offered efficient catalysis for the hydrolysis of cellulose and the dehydration of the sorbitol hydroxyl moiety.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1039/c4ra14304c
研究领域[WOS]Chemistry
关键词[WOS]TRANSITION-METAL OXIDE ; SOLID ACID CATALYSTS ; ONE-POT CONVERSION ; NI/HZSM-5 CATALYSTS ; ETHYLENE-GLYCOL ; GLYCOLALDEHYDE PHOSPHATE ; LIQUID ALKANES ; C-6 ALDITOLS ; RANEY NI ; BIOMASS
收录类别SCI
语种英语
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000348986900095
引用统计
被引频次:16[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10805
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Liu, Yong,Chen, Lungang,Wang, Tiejun,et al. High yield of renewable hexanes by direct hydrolysis-hydrodeoxygenation of cellulose in an aqueous phase catalytic system[J]. RSC ADVANCES,2015,5(15):11649-11657.
APA Liu, Yong.,Chen, Lungang.,Wang, Tiejun.,Zhang, Xinghua.,Long, Jinxing.,...&Ma, Longlong.(2015).High yield of renewable hexanes by direct hydrolysis-hydrodeoxygenation of cellulose in an aqueous phase catalytic system.RSC ADVANCES,5(15),11649-11657.
MLA Liu, Yong,et al."High yield of renewable hexanes by direct hydrolysis-hydrodeoxygenation of cellulose in an aqueous phase catalytic system".RSC ADVANCES 5.15(2015):11649-11657.
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