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Enhancement of photovoltaic performance of TiO2-based dye-sensitized solar cells by doping Ca3La3(1-x)Eu3x(BO3)(5)
Dai, W. B.1; Lei, Y. F.2; Li, P.3; Xu, L. F.4
2015
发表期刊JOURNAL OF MATERIALS CHEMISTRY A
卷号3期号:9页码:4875-4883
摘要A series of Ca3La3(1-x)Eu3x(BO3)(5) (CLBO:3xEu(3+)) phosphors were prepared by the Pechini-type sol-gel technique. Rietveld refinement was performed using the powder X-ray diffraction data, which shows the occupation of Eu3+ on both Ca2+ and La3+ sites with a preferred location on the La3+ site over the Ca2+ site. In order to enhance the photovoltaic performance of dye-sensitized solar cells (DSSCs), a novel design is demonstrated by introducing CLBO:3xEu(3+) in TiO2-based DSSC. As a new conversion luminescence medium, CLBO:3xEu(3+) transfers ultraviolet light to visible light via down-conversion, and increases the solar light harvest and photocurrent of DSSC. The experimental results reveal the feasibility of the conversion luminescence by doping rare-earth phosphors in the DSSC, providing an effective novel method to improve the sunlight conversion efficiency for solar cells.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1039/c4ta05723f
研究领域[WOS]Chemistry ; Energy & Fuels ; Materials Science
关键词[WOS]PHOTOLUMINESCENCE CHARACTERISTICS ; LUMINESCENCE PROPERTIES ; PHOSPHORS ; EFFICIENCY ; SPECTROSCOPY ; CA3LA3(BO3)(5) ; RECOMBINATION ; ELECTROLYTE ; TRANSPORT
收录类别SCI
语种英语
WOS类目Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS记录号WOS:000349997000015
引用统计
被引频次:21[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10790
专题中国科学院广州能源研究所
作者单位1.S China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China
2.Natl Ctr Nanosci & Technol, State Key Lab Biol Effects Nanomat & Nanosafety, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
4.S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510640, Guangdong, Peoples R China
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Dai, W. B.,Lei, Y. F.,Li, P.,et al. Enhancement of photovoltaic performance of TiO2-based dye-sensitized solar cells by doping Ca3La3(1-x)Eu3x(BO3)(5)[J]. JOURNAL OF MATERIALS CHEMISTRY A,2015,3(9):4875-4883.
APA Dai, W. B.,Lei, Y. F.,Li, P.,&Xu, L. F..(2015).Enhancement of photovoltaic performance of TiO2-based dye-sensitized solar cells by doping Ca3La3(1-x)Eu3x(BO3)(5).JOURNAL OF MATERIALS CHEMISTRY A,3(9),4875-4883.
MLA Dai, W. B.,et al."Enhancement of photovoltaic performance of TiO2-based dye-sensitized solar cells by doping Ca3La3(1-x)Eu3x(BO3)(5)".JOURNAL OF MATERIALS CHEMISTRY A 3.9(2015):4875-4883.
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