Synthesis of mesoporous Co-Ce oxides catalysts by glycine-nitrate combustion approach for CO preferential oxidation reaction in excess H-2

doi:10.1016/j.ijhydene.2014.01.024

GIEC OpenIR > 中国科学院广州能源研究所

	Synthesis of mesoporous Co-Ce oxides catalysts by glycine-nitrate combustion approach for CO preferential oxidation reaction in excess H-2
	Yan, Chang-Feng1,2 ; Chen, Hao 1,3; Hu, Rong-Rong 1; Huang, Shilin 1; Luo, Weimin1 ; Guo, Changqing1 ; Li, Mingyu 3; Li, Wenbo1
	2014-10-31
发表期刊	INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷号	39 期号:32 页码:18695-18701
摘要	Preferential oxidation of CO (CO-PrOx) is an important step to meet the need of the proton exchange membrane (PEM) fuel cell without the Pt anion poison. A glycine-nitrate approach was used for the synthesis of Co/CeO2 nanoparticle for preferential oxidation of CO, which a precursor solution was prepared by mixing glycine with an aqueous solution of blended nitrate in stoichiometric ratio. Then the glycine-mixed precursor solution was heated in a beaker for producing nanosized porous powders. Catalytic properties of the powders were investigated and results illustrate that the Co-loading of 30 wt.% catalysts exhibits excellent catalytic properties. Various characterization techniques like X-ray diffraction, SEM, BET, Raman and TPR were used to analyze the relationship between catalyst nature and catalytic performance. The X-ray diffraction patterns and SEM micrographs indicate that catalysts prepared by glycine-nitrate combustion own mesopore structure. The BET, Raman and TPR results showed that the high activity of the 30 wt.% Co-loading of Co/CeO2 catalysts is related to the high BET surface and the strongly interaction between fine-dispersed Co species and CeO2 support. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
文章类型	Article
关键词	Co-prox Glycine-nitrate Combustion Co/ceo2 Catalyst
WOS标题词	Science & Technology ; Physical Sciences ; Technology
DOI	10.1016/j.ijhydene.2014.01.024
研究领域[WOS]	Chemistry ; Electrochemistry ; Energy & Fuels
关键词[WOS]	CARBON-MONOXIDE OXIDATION ; HYDROGEN-RICH STREAM ; CO3O4-CEO2 CATALYSTS ; SELECTIVE OXIDATION ; STRUCTURAL-CHARACTERIZATION ; CUO-CEO2 CATALYSTS ; REACTION-MECHANISM ; ACTIVE CATALYSTS ; H-2-RICH GASES ; O COMPOSITE
收录类别	SCI
语种	英语
WOS类目	Chemistry, Physical ; Electrochemistry ; Energy & Fuels
WOS记录号	WOS:000345804600059
引用统计	被引频次：33[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10757
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Jinan Univ, Dept Environm Engn, Guangzhou 510632, Guangdong, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Yan, Chang-Feng,Chen, Hao,Hu, Rong-Rong,et al. Synthesis of mesoporous Co-Ce oxides catalysts by glycine-nitrate combustion approach for CO preferential oxidation reaction in excess H-2[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2014,39(32):18695-18701.
APA	Yan, Chang-Feng.,Chen, Hao.,Hu, Rong-Rong.,Huang, Shilin.,Luo, Weimin.,...&Li, Wenbo.(2014).Synthesis of mesoporous Co-Ce oxides catalysts by glycine-nitrate combustion approach for CO preferential oxidation reaction in excess H-2.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,39(32),18695-18701.
MLA	Yan, Chang-Feng,et al."Synthesis of mesoporous Co-Ce oxides catalysts by glycine-nitrate combustion approach for CO preferential oxidation reaction in excess H-2".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 39.32(2014):18695-18701.