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Production of hydrogen rich bio-oil derived syngas from co-gasification of bio-oil and waste engine oil as feedstock for lower alcohols synthesis in two-stage bed reactor
Guo, Haijun1,2; Peng, Fen1,2; Zhang, Hairong1,2; Xiong, Lian1,2; Li, Shanggui3,4; Wang, Can1,2; Wang, Bo1,2,3; Chen, Xinde1,2; Chen, Yong1
2014-06-05
发表期刊INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷号39期号:17页码:9200-9211
摘要High efficient production of lower alcohols (C-1-C-5 mixed alcohols) from hydrogen rich bio-oil derived syngas was achieved in this work. A non-catalytic partial oxidation (NPDX) gasification technology was successfully applied in the production and conditioning of bio-oil derived syngas using bio-oil (BO) and emulsifying waste engine oil (EWEO) as feedstock. The effects of water addition and feedstock composition on the gasification performances were investigated. When the BO20 and EWEO30 was mixed with mass ratio of 1: 0.33, the maximum hydrogen yield of 93.7% with carbon conversion of 96.7% was obtained, and the hydrogen rich bio-oil derived syngas was effectively produced. Furthermore, a two-stage bed reactor was applied in the downstream process of lower alcohols synthesis from hydrogen rich bio-oil derived syngas (H-2/CO/CO2/CH4/N-2 = 52.2119.513.0/9.4/15.9, v/v). The highest carbon conversion of 42.5% and the maximum alcohol yield of 0.18 kg/kg(cat) h with selectivity of 53.8 wt% were obtained over the Cu/ZnO/Al2O3(2.5)//Cu25Fe22Co3K3/SiO2(2.5) catalyst combination system. The mechanism and evaluation for lower alcohols synthesis from model bio-oil derived syngas and model mixture gas were also discussed. The integrative process of hydrogen rich bio-oil derived syngas production and downstream lower alcohols synthesis, potentially providing a promising route for the conversion of organic wastes into high performance fuels and high value-added chemicals. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
文章类型Article
关键词Hydrogen Rich Bio-oil Derived Syngas Non-catalytic Partial Oxidation Gasification Bio-oil Waste Engine Oil Lower Alcohols
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1016/j.ijhydene.2014.04.008
研究领域[WOS]Chemistry ; Electrochemistry ; Energy & Fuels
关键词[WOS]MICROWAVE-HEATED PYROLYSIS ; CATALYTIC SYNTHESIS ; SYNTHESIS GAS ; GASEOUS FUEL ; CHAIN GROWTH ; BIOMASS ; CONVERSION ; METHANOL ; KINETICS ; CU/ZNO
收录类别SCI
语种英语
WOS类目Chemistry, Physical ; Electrochemistry ; Energy & Fuels
WOS记录号WOS:000336880500032
引用统计
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10744
专题中国科学院广州能源研究所
集成技术研发中心
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, R&D Ctr Xuyi Attapulgite Appl Technol, Xuyi 211700, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
4.China Nucl Power Design Co Ltd, Dept Informat Dev, Shenzhen 518052, Peoples R China
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Guo, Haijun,Peng, Fen,Zhang, Hairong,et al. Production of hydrogen rich bio-oil derived syngas from co-gasification of bio-oil and waste engine oil as feedstock for lower alcohols synthesis in two-stage bed reactor[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2014,39(17):9200-9211.
APA Guo, Haijun.,Peng, Fen.,Zhang, Hairong.,Xiong, Lian.,Li, Shanggui.,...&Chen, Yong.(2014).Production of hydrogen rich bio-oil derived syngas from co-gasification of bio-oil and waste engine oil as feedstock for lower alcohols synthesis in two-stage bed reactor.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,39(17),9200-9211.
MLA Guo, Haijun,et al."Production of hydrogen rich bio-oil derived syngas from co-gasification of bio-oil and waste engine oil as feedstock for lower alcohols synthesis in two-stage bed reactor".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 39.17(2014):9200-9211.
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