Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Production of Hydrocarbons via Hydrodeoxygenation of Lignin-Derived Phenolic Compounds | |
Zhang Xinghua; Chen Lungang; Zhang Qi; Long Jinxing; Wang Tiejun; Ma Longlong | |
2014-12-01 | |
发表期刊 | PROGRESS IN CHEMISTRY |
卷号 | 26期号:12页码:1997-2006 |
摘要 | Lignin is the component with the highest carbon content in biomass. The transformation of lignin to high-grade liquid fuels can be achieved via hydrodeoxygenation(HDO) of phenolic intermediates derived from the products of lignin depolymerization. The octane numbers of the hydrodeoxygenation products of phenolic intermediates are quite high. They have vapor pressures and carbon atom number (C6 similar to C10) within the range of gasoline. Thus, these hydrodeoxygenation products would be the most desirable components for a fungible liquid transportation fuel. This is very meaningful to application of lignin. Recently, researches about the hydrodeoxygenation of phenolic compounds develop rapidly. In this paper, the HDO reactions of phenolic compounds using sulfided Mo-based catalyst, noble metal catalyst and inexpensive non-sulfided catalyst are reviewed in detail. It is found that most of the investigated catalysts are bifunctional catalysts, combining the hydrogenation function of active metal with hydrolysis and dehydration of support. The catalytic mechanism for the HDO of phenolic compounds is sketched, and the effects of catalyst supporter on the catalytic activity are also discussed. Furthermore, the current technique challenges are summarized, and future technologic explorations for the efficient hydrodeoxygenation of lignin-derived phenolic compounds are proposed. |
文章类型 | Article |
关键词 | Lignin Phenolic Compounds Hydrocarbons Hydrodeoxygenation Active Metal Supporter |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.7536/PC140815 |
研究领域[WOS] | Chemistry |
关键词[WOS] | B AMORPHOUS CATALYSTS ; NOBLE-METAL CATALYSTS ; NI-BASED CATALYSTS ; BIO-OIL ; PYROLYSIS OIL ; HYDRODESULFURIZATION CATALYSTS ; SUPPORTED PALLADIUM ; GUAIACOL HYDRODEOXYGENATION ; SULFIDED COMO/GAMMA-AL2O3 ; SELECTIVE HYDROGENATION |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Chemistry, Multidisciplinary |
WOS记录号 | WOS:000348006500010 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10742 |
专题 | 中国科学院广州能源研究所 |
作者单位 | Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang Xinghua,Chen Lungang,Zhang Qi,et al. Production of Hydrocarbons via Hydrodeoxygenation of Lignin-Derived Phenolic Compounds[J]. PROGRESS IN CHEMISTRY,2014,26(12):1997-2006. |
APA | Zhang Xinghua,Chen Lungang,Zhang Qi,Long Jinxing,Wang Tiejun,&Ma Longlong.(2014).Production of Hydrocarbons via Hydrodeoxygenation of Lignin-Derived Phenolic Compounds.PROGRESS IN CHEMISTRY,26(12),1997-2006. |
MLA | Zhang Xinghua,et al."Production of Hydrocarbons via Hydrodeoxygenation of Lignin-Derived Phenolic Compounds".PROGRESS IN CHEMISTRY 26.12(2014):1997-2006. |
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