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Production of Hydrocarbons via Hydrodeoxygenation of Lignin-Derived Phenolic Compounds
Zhang Xinghua; Chen Lungang; Zhang Qi; Long Jinxing; Wang Tiejun; Ma Longlong
2014-12-01
发表期刊PROGRESS IN CHEMISTRY
卷号26期号:12页码:1997-2006
摘要Lignin is the component with the highest carbon content in biomass. The transformation of lignin to high-grade liquid fuels can be achieved via hydrodeoxygenation(HDO) of phenolic intermediates derived from the products of lignin depolymerization. The octane numbers of the hydrodeoxygenation products of phenolic intermediates are quite high. They have vapor pressures and carbon atom number (C6 similar to C10) within the range of gasoline. Thus, these hydrodeoxygenation products would be the most desirable components for a fungible liquid transportation fuel. This is very meaningful to application of lignin. Recently, researches about the hydrodeoxygenation of phenolic compounds develop rapidly. In this paper, the HDO reactions of phenolic compounds using sulfided Mo-based catalyst, noble metal catalyst and inexpensive non-sulfided catalyst are reviewed in detail. It is found that most of the investigated catalysts are bifunctional catalysts, combining the hydrogenation function of active metal with hydrolysis and dehydration of support. The catalytic mechanism for the HDO of phenolic compounds is sketched, and the effects of catalyst supporter on the catalytic activity are also discussed. Furthermore, the current technique challenges are summarized, and future technologic explorations for the efficient hydrodeoxygenation of lignin-derived phenolic compounds are proposed.
文章类型Article
关键词Lignin Phenolic Compounds Hydrocarbons Hydrodeoxygenation Active Metal Supporter
WOS标题词Science & Technology ; Physical Sciences
DOI10.7536/PC140815
研究领域[WOS]Chemistry
关键词[WOS]B AMORPHOUS CATALYSTS ; NOBLE-METAL CATALYSTS ; NI-BASED CATALYSTS ; BIO-OIL ; PYROLYSIS OIL ; HYDRODESULFURIZATION CATALYSTS ; SUPPORTED PALLADIUM ; GUAIACOL HYDRODEOXYGENATION ; SULFIDED COMO/GAMMA-AL2O3 ; SELECTIVE HYDROGENATION
收录类别SCI
语种英语
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000348006500010
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10742
专题中国科学院广州能源研究所
作者单位Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
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GB/T 7714
Zhang Xinghua,Chen Lungang,Zhang Qi,et al. Production of Hydrocarbons via Hydrodeoxygenation of Lignin-Derived Phenolic Compounds[J]. PROGRESS IN CHEMISTRY,2014,26(12):1997-2006.
APA Zhang Xinghua,Chen Lungang,Zhang Qi,Long Jinxing,Wang Tiejun,&Ma Longlong.(2014).Production of Hydrocarbons via Hydrodeoxygenation of Lignin-Derived Phenolic Compounds.PROGRESS IN CHEMISTRY,26(12),1997-2006.
MLA Zhang Xinghua,et al."Production of Hydrocarbons via Hydrodeoxygenation of Lignin-Derived Phenolic Compounds".PROGRESS IN CHEMISTRY 26.12(2014):1997-2006.
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