Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
One-Pot Transformation of Cellulose to Sugar Alcohols over Acidic Metal Phosphates Combined with Ru/C | |
Liu, Qi-Ying1; Liao, Yu-He1,2; Wang, Tie-Jun1; Cai, Chi-Liu1; Zhang, Qi1; Tsubaki, Noritatsu3; Ma, Long-Long1 | |
2014-08-13 | |
发表期刊 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH |
卷号 | 53期号:32页码:12655-12664 |
摘要 | ZrP with large surface, mesoporous volume, and size was prepared. Its catalytic performance was evaluated in hydrolytic hydrogenation of cellulose to sorbitol/mannitol combined with commercial Ru/C. A significantly enhanced sorbitol/mannitol yield was obtained as compared with that of the water-soluble acidic phosphates and buffer solution of potassium acid phthalate combined with the same Ru/C. The enhanced yield was attributed to the Lewis and Bronsted acid on ZrP surface improving the surface's absorption and activation for cellulose and accelerating the rate-determined hydrolysis step. The maximal sorbitol/mannitol yield of 63% and 81% could be obtained by using microcrystalline and ball milling cellulose as the feedstock, respectively. The ZrP combined with Ru/C was adaptable to the high concentrated cellulose and obtained 5.8 wt % of sorbitol/mannitol concentration. The remarkably enhanced cellulose hydrolysis by ZrP sharply decreased the use of Ru/C, which is significant for the essential application. |
文章类型 | Article |
WOS标题词 | Science & Technology ; Technology |
DOI | 10.1021/ie5016238 |
研究领域[WOS] | Engineering |
关键词[WOS] | ZIRCONIUM HYDROGEN PHOSPHATE ; HIGH-SURFACE-AREA ; CATALYTIC CONVERSION ; SOLID ACID ; MICROCRYSTALLINE CELLULOSE ; LIGNOCELLULOSIC BIOMASS ; AQUEOUS-SOLUTION ; DEHYDRATION ; SORBITOL ; WATER |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Engineering, Chemical |
WOS记录号 | WOS:000340441000012 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10741 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Toyama Univ, Sch Engn, Dept Appl Chem, Toyama 9308555, Japan |
第一作者单位 | 中国科学院广州能源研究所 |
推荐引用方式 GB/T 7714 | Liu, Qi-Ying,Liao, Yu-He,Wang, Tie-Jun,et al. One-Pot Transformation of Cellulose to Sugar Alcohols over Acidic Metal Phosphates Combined with Ru/C[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2014,53(32):12655-12664. |
APA | Liu, Qi-Ying.,Liao, Yu-He.,Wang, Tie-Jun.,Cai, Chi-Liu.,Zhang, Qi.,...&Ma, Long-Long.(2014).One-Pot Transformation of Cellulose to Sugar Alcohols over Acidic Metal Phosphates Combined with Ru/C.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,53(32),12655-12664. |
MLA | Liu, Qi-Ying,et al."One-Pot Transformation of Cellulose to Sugar Alcohols over Acidic Metal Phosphates Combined with Ru/C".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 53.32(2014):12655-12664. |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论