Aviation fuel synthesis by catalytic conversion of biomass hydrolysate in aqueous phase

doi:10.1016/j.apenergy.2014.06.035

GIEC OpenIR > 中国科学院广州能源研究所

	Aviation fuel synthesis by catalytic conversion of biomass hydrolysate in aqueous phase
	Wang, Tiejun; Li, Kai; Liu, Qiying; Zhang, Qing; Qiu, Songbai; Long, Jinxing; Chen, Lungang; Ma, Longlong; Zhang, Qi
	2014-12-31
发表期刊	APPLIED ENERGY
卷号	136 页码:775-780
摘要	This paper presents a new route for biomass derived aviation fuel synthesis by catalytic conversion in aqueous phase. Furfural with the yield of 71% was produced by acid hydrolysis of raw corncob, and hydrogenated to 2-methylfuran with obtaining the yield of 89% over Raney Ni catalyst, both of which were implemented under mild reaction conditions. The hydroxyalkylation/alkylation condensation of 2-methylfuran and furfural to C-15 intermediate was conducted by using organic and inorganic acid as the catalyst under the reaction condition of 328 K and atmospheric pressure. The maximal 95% of the C-15 intermediate was gained when using sulfuric acid as the catalyst. 83% of liquid alkanes (C-8-C-15) yield and more than 90% of C-14/C-15 selectivity were produced by hydrodeoxygenation of the C-15 intermediate over 10 wt%Ni/ZrO2-SiO2 catalyst. During the hydrodeoxygenation process, the catalyst showed excellent stability depended on the 110 h of time-on-stream test, due to its significantly decreased carbon deposition. (C) 2014 Elsevier Ltd. All rights reserved.
文章类型	Article
关键词	Aviation Fuel Aqueous Phase Catalytic Conversion Biomass Hydrolysate
WOS标题词	Science & Technology ; Technology
DOI	10.1016/j.apenergy.2014.06.035
研究领域[WOS]	Energy & Fuels ; Engineering
关键词[WOS]	RENEWABLE DIESEL ; LIQUID ALKANES ; VEGETABLE-OILS ; HYDROCARBONS ; GAS
收录类别	SCI
语种	英语
WOS类目	Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:000345725800075
引用统计	被引频次：60[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10700
专题	中国科学院广州能源研究所
作者单位	Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Wang, Tiejun,Li, Kai,Liu, Qiying,et al. Aviation fuel synthesis by catalytic conversion of biomass hydrolysate in aqueous phase[J]. APPLIED ENERGY,2014,136:775-780.
APA	Wang, Tiejun.,Li, Kai.,Liu, Qiying.,Zhang, Qing.,Qiu, Songbai.,...&Zhang, Qi.(2014).Aviation fuel synthesis by catalytic conversion of biomass hydrolysate in aqueous phase.APPLIED ENERGY,136,775-780.
MLA	Wang, Tiejun,et al."Aviation fuel synthesis by catalytic conversion of biomass hydrolysate in aqueous phase".APPLIED ENERGY 136(2014):775-780.