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Zirconium phosphate combined with Ru/C as a highly efficient catalyst for the direct transformation of cellulose to C-6 alditols
Liao, Yuhe1,2; Liu, Qiying1; Wang, Tiejun1; Long, Jinxing1; Ma, Longlong1; Zhang, Qi1
2014
发表期刊GREEN CHEMISTRY
卷号16期号:6页码:3305-3312
摘要The selective transformation of cellulose to C-6 alditols provides a feasible route towards the sustainable synthesis of chemicals and fuels. Herein, the catalytic performance of amorphous zirconium phosphate (ZPA) combined with 5 wt% Ru/C was evaluated in the direct conversion of cellulose to C-6 alditols (sorbitol and mannitol) under hydrothermal conditions. The yield of C-6 alditols reached 63.5% and 85.5% with microcrystalline cellulose and ball-milled cellulose as the feedstock, respectively. This hybrid catalyst was developed to convert concentrated cellulose to obtain C-6 alditols with a high concentration of 68.8 mg mL(-1) in the final products. The high yield of C-6 alditols from cellulose was ascribed to the fact that ZPA favoured the adsorption of cellulose and promoted its depolymerization to cellobiose and glucose, which was hydrogenated immediately to C-6 alditols over Ru/C. The weak adsorption of C-6 alditols over ZPA inhibited the dehydration of C-6 alditols to sorbitan. Furthermore, ZPA exhibited excellent hydrothermal stability and could be reused for several runs.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1039/c3gc42444h
研究领域[WOS]Chemistry
关键词[WOS]AQUEOUS-PHASE HYDRODEOXYGENATION ; SOLID ACID CATALYSTS ; SUGAR ALCOHOLS ; GLUCOSE DEHYDRATION ; BIPHASIC SYSTEM ; ETHYLENE-GLYCOL ; LEVULINIC ACID ; CONVERSION ; BIOMASS ; CELLOBIOSE
收录类别SCI
语种英语
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000336836100046
引用统计
被引频次:43[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10699
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Liao, Yuhe,Liu, Qiying,Wang, Tiejun,et al. Zirconium phosphate combined with Ru/C as a highly efficient catalyst for the direct transformation of cellulose to C-6 alditols[J]. GREEN CHEMISTRY,2014,16(6):3305-3312.
APA Liao, Yuhe,Liu, Qiying,Wang, Tiejun,Long, Jinxing,Ma, Longlong,&Zhang, Qi.(2014).Zirconium phosphate combined with Ru/C as a highly efficient catalyst for the direct transformation of cellulose to C-6 alditols.GREEN CHEMISTRY,16(6),3305-3312.
MLA Liao, Yuhe,et al."Zirconium phosphate combined with Ru/C as a highly efficient catalyst for the direct transformation of cellulose to C-6 alditols".GREEN CHEMISTRY 16.6(2014):3305-3312.
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