All-Solid-State Lithium Organic Battery with Composite Polymer Electrolyte and Pillar[5]quinone Cathode

doi:10.1021/ja507852t

GIEC OpenIR > 中国科学院广州能源研究所

	All-Solid-State Lithium Organic Battery with Composite Polymer Electrolyte and Pillar[5]quinone Cathode
	Zhu, Zhiqiang 1,2; Hong, Meiling 1,2; Guo, Dongsheng 1,2; Shi, Jifu 3; Tao, Zhanliang 1,2; Chen, Jun 1,2
	2014-11-26
发表期刊	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷号	136 期号:47 页码:16461-16464
摘要	The cathode capacity of common lithium ion batteries (LIBs) using inorganic electrodes and liquid electrolytes must be further improved. Alternatively, all-solid-state lithium batteries comprising the electrode of organic compounds can offer much higher capacity. Herein, we successfully fabricated an all-solid-state lithium battery based on organic pillar[5]quinone (C35H20O10) cathode and composite polymer electrolyte (CPE). The poly(methacrylate) (PMA)/poly(ethylene glycol) (PEG)-LiClO4-3 wt % SiO2 CPE has an optimum ionic conductivity of 0.26 mS cm(-1) at room temperature. Furthermore, pillar[5]quinine cathode in all-solid-state battery rendered an average operation voltage of similar to 2.6 V and a high initial capacity of 418 mAh g(-1) with a stable cyclability (94.7% capacity retention after 50 cycles at 0.2C rate) through the reversible redox reactions of enolate/quinonid carbonyl groups, showing favorable prospect for the device application with high capacity.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1021/ja507852t
研究领域[WOS]	Chemistry
关键词[WOS]	SOGGY SAND ELECTROLYTES ; LI-ION BATTERIES ; ENERGY-STORAGE ; SALT-SOLUTIONS ; OXIDE)
收录类别	SCI
语种	英语
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000345720500001
引用统计	被引频次：353[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10696
专题	中国科学院广州能源研究所
作者单位	1.Nankai Univ, Coll Chem, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin 300071, Peoples R China 2.Nankai Univ, Coll Chem, State Key Lab Elementoorgan Chem, Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300071, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Peoples R China
推荐引用方式 GB/T 7714	Zhu, Zhiqiang,Hong, Meiling,Guo, Dongsheng,et al. All-Solid-State Lithium Organic Battery with Composite Polymer Electrolyte and Pillar[5]quinone Cathode[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2014,136(47):16461-16464.
APA	Zhu, Zhiqiang,Hong, Meiling,Guo, Dongsheng,Shi, Jifu,Tao, Zhanliang,&Chen, Jun.(2014).All-Solid-State Lithium Organic Battery with Composite Polymer Electrolyte and Pillar[5]quinone Cathode.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,136(47),16461-16464.
MLA	Zhu, Zhiqiang,et al."All-Solid-State Lithium Organic Battery with Composite Polymer Electrolyte and Pillar[5]quinone Cathode".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 136.47(2014):16461-16464.