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The oriented growth of tungsten oxide in ordered mesoporous carbon and their electrochemical performance
Wang, Tao1; Tang, Jing2; Fan, Xiaoli1; Zhou, Jianhua3; Xue, Hairong1; Guo, Hu1; He, Jianping1
2014
发表期刊NANOSCALE
卷号6期号:10页码:5359-5371
摘要Electrocatalysts for hydrogen oxidation and methanol oxidation are the heart of the proton exchange membrane fuel cell. In spite of tremendous efforts, developing low-cost anodic electrocatalysts with high catalytic activity and corrosion resistance is still a great challenge. Here, we report a nanocomposite consisting of oriented WO3 nanorods grown in ordered mesoporous carbon as a high-performance functional catalyst carrier for proton exchange membrane fuel cells. As a result of the catalytic graphitization effect of tungsten compounds, the degree of graphitization and conductivity of mesoporous carbon film were improved even at a low temperature. Furthermore, compared with ordered mesoporous carbon, ordered mesoporous C-WO3 nanocomposites possess favorable hydrophilicity, excellent corrosion resistance and notable electrocatalytic activities. The unusual electrocatalytic activities arise from the ideal physical properties of the carrier and synergetic catalysis between Pt and WO3.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1039/c4nr00396a
研究领域[WOS]Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
关键词[WOS]TRANSITION-METAL CARBIDES ; HIGH THERMAL-STABILITY ; CATALYTIC GRAPHITIZATION ; METHANOL OXIDATION ; FUEL-CELLS ; OXYGEN REDUCTION ; ELECTROCATALYTIC ACTIVITY ; AMORPHOUS-CARBON ; NANOPARTICLES ; SILICA
收录类别SCI
语种英语
WOS类目Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
WOS记录号WOS:000335148800047
引用统计
被引频次:34[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10687
专题中国科学院广州能源研究所
作者单位1.Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Technol, Nanjing 210016, Jiangsu, Peoples R China
2.Waseda Univ, Fac Sci & Engn, Dept Nanosci & Nanoengn, Shinjuku Ku, Tokyo 1698555, Japan
3.Chinese Acad Sci, Guangzhou Inst Energy Convers, China Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Peoples R China
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Wang, Tao,Tang, Jing,Fan, Xiaoli,et al. The oriented growth of tungsten oxide in ordered mesoporous carbon and their electrochemical performance[J]. NANOSCALE,2014,6(10):5359-5371.
APA Wang, Tao.,Tang, Jing.,Fan, Xiaoli.,Zhou, Jianhua.,Xue, Hairong.,...&He, Jianping.(2014).The oriented growth of tungsten oxide in ordered mesoporous carbon and their electrochemical performance.NANOSCALE,6(10),5359-5371.
MLA Wang, Tao,et al."The oriented growth of tungsten oxide in ordered mesoporous carbon and their electrochemical performance".NANOSCALE 6.10(2014):5359-5371.
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