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Three-dimensionally ordered macroporous LaFeO3 perovskites for chemical-looping steam reforming of methane
Zhao, Kun1,2; He, Fang1; Huang, Zhen1; Zheng, Anqing1; Li, Haibin1; Zhao, Zengli1
2014-02-25
Source PublicationINTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume39Issue:7Pages:3243-3252
AbstractThree-dimensionally ordered macroporous (3DOM) LaFeO3 and nano-LaFeO3 perovskitetype oxides were synthesized by impregnation of polystyrene (PS) templates and combustion method, respectively. The obtained LaFeO3 perovskites were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Brunauer Emmett Teller (BET) surface area, and hydrogen-temperature programmed reduction (H-2-TPR). The performance of the perovsldtes as oxygen carriers in chemical looping steam methane reforming (CL-SMR) to produce syngas (H-2 + CO) and hydrogen were investigated. The synthesized 3DOM-LaFeO3 was pure crystalline perovskite giving a surface area of 8.088 m(2)/g, higher than that of nano-LaFeO3 particles (4.323 m(2)/g). In the methane reduction stage, methane was partially oxidized into syngas at a H-2/CO molar ratio close to 2:1 by the 3DOM-LaFeO3 in the main stage of the reactions. In the steam oxidation stage, the reduced perovskites were oxidized by steam to generate hydrogen simultaneously. No significant decrease of the yields of syngas and hydrogen was observed during ten successive redox cycles, indicating that the 3DOM-LaFeO3 perovskites have good repeatability. In comparison to nano-LaFeO3, 3DOM-LaFeO3 has more stable reactivity of methane oxidation and better resistance to carbon formation. In spite of a part of 3DOM structure were collapsed in the course of the cyclic reactions, the specific surface area of the 3DOMLaFeO(3) was still higher than that of the nano one. The better reactivity of 3DOM-LaFeO3 compared with that of nano-LaFeO3 is partially attributed to the higher surface area. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
SubtypeArticle
Keyword3dom Perovskite Chemical-looping Steam Methane Reforming Syngas Hydrogen
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1016/j.ijhydene.2013.12.046
WOS Subject ExtendedChemistry ; Electrochemistry ; Energy & Fuels
WOS KeywordHYDROGEN-PRODUCTION ; OXYGEN CARRIERS ; COMBUSTION ; PERFORMANCE ; CRYSTAL ; OXIDES ; TECHNOLOGIES ; CATALYST ; CO
Indexed BySCI
Language英语
WOS SubjectChemistry, Physical ; Electrochemistry ; Energy & Fuels
WOS IDWOS:000331917400021
Citation statistics
Cited Times:45[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10679
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Zhao, Kun,He, Fang,Huang, Zhen,et al. Three-dimensionally ordered macroporous LaFeO3 perovskites for chemical-looping steam reforming of methane[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2014,39(7):3243-3252.
APA Zhao, Kun,He, Fang,Huang, Zhen,Zheng, Anqing,Li, Haibin,&Zhao, Zengli.(2014).Three-dimensionally ordered macroporous LaFeO3 perovskites for chemical-looping steam reforming of methane.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,39(7),3243-3252.
MLA Zhao, Kun,et al."Three-dimensionally ordered macroporous LaFeO3 perovskites for chemical-looping steam reforming of methane".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 39.7(2014):3243-3252.
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