Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Water-Soluble Conductive Composite Binder Containing PEDOT: PSS as Conduction Promoting Agent for Si Anode of Lithium-Ion Batteries | |
Shao, Dan1,2; Zhong, Haoxiang1; Zhang, Lingzhi1 | |
2014-10-14 | |
发表期刊 | CHEMELECTROCHEM |
卷号 | 1期号:10页码:1679-1687 |
摘要 | A novel water-soluble conductive composite binder consisting of carboxymethyl cellulose (CMC) as binder and aqueous poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as conduction-promoting agent is reported for the Si anode of Li-ion batteries. The introduction of conductive PEDOT:PSS into a water-soluble binder facilitates the formation of homogenous and continuous conducting bridges throughout the electrode and increases the compaction density of the electrode by reducing the content of the commonly used conducting agent of acetylene black. Galvanostatic testing, cyclic voltammetry and electrochemical impedance spectroscopy measurements show that the electrodes using the composite binder exhibit higher initial Coulombic efficiencies, better cycling and rate performance, and more favorable electrochemical kinetics compared with the electrodes using CMC binder with acetylene black conducting agent. |
文章类型 | Article |
关键词 | Batteries Conducting Polymers Electrodes Pedot:Pss Water-soluble Binders |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1002/celc.201402210 |
研究领域[WOS] | Electrochemistry |
关键词[WOS] | MULTIWALLED CARBON NANOTUBES ; NEGATIVE ELECTRODES ; HIGH-CAPACITY ; ELECTROCHEMICAL PERFORMANCE ; CARBOXYMETHYL CHITOSAN ; SILICON NANOWIRES ; CATHODE MATERIAL ; NANOCOMPOSITE ; INSERTION ; HYBRID |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Electrochemistry |
WOS记录号 | WOS:000343760900014 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10677 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
第一作者单位 | 中国科学院广州能源研究所 |
推荐引用方式 GB/T 7714 | Shao, Dan,Zhong, Haoxiang,Zhang, Lingzhi. Water-Soluble Conductive Composite Binder Containing PEDOT: PSS as Conduction Promoting Agent for Si Anode of Lithium-Ion Batteries[J]. CHEMELECTROCHEM,2014,1(10):1679-1687. |
APA | Shao, Dan,Zhong, Haoxiang,&Zhang, Lingzhi.(2014).Water-Soluble Conductive Composite Binder Containing PEDOT: PSS as Conduction Promoting Agent for Si Anode of Lithium-Ion Batteries.CHEMELECTROCHEM,1(10),1679-1687. |
MLA | Shao, Dan,et al."Water-Soluble Conductive Composite Binder Containing PEDOT: PSS as Conduction Promoting Agent for Si Anode of Lithium-Ion Batteries".CHEMELECTROCHEM 1.10(2014):1679-1687. |
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